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Preparation of anatase T1O2 nanoparticles using low hydrothermal temperature for dye-sensitized solar cell

机译:染料敏化太阳能电池低水热温锐钛矿T1O2纳米粒子的制备

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One device being developed as an alternative source of renewable energy by utilizing solar energy source is dye-sensitized solar cells (DSSC). This device works using simple photosynthetic-electrochemical principle in the molecular level. In this device, the inorganic oxide semiconductor of titanium dioxide (TiO2) has a great potential for the absorption of the photon energy from the solar energy source, especially in the form of TiO2 nanoparticle structure. This nanoparticle structure is expected to improve the performance of DSSC because the surface area to weight ratio of this nanostructures is very large. In this study, the synthesis of TiC2 nanoparticle from its precursors has been performed along with the fabrication of the DSSC device. Effort to improve the size of nanocrystalline anatase TiO2 was accomplished by low hydrothermal treatment at various temperatures whereas the crystallinity of the anatase phase in the structure was performed by calcination process. Characterization of the materials was performed using X-ray Diffraction (XRD) and scanning electron microscope (SEM), while the DSSC performance was examined through a high precision current versus voltage (I-V) curve analyzer. The results showed that pure anatase TiO2 nanoparticles could be obtained at low hydrothermal of 100, 125, and 150 °C followed by calcination at 450 °C. The best performance of photocurrent-voltage characteristic was given by TiO2 hydrothermally synthesized at 150 °C with power conversion efficiency (PCE) of 4.40 %, whereas the standard TiO2 nanoparticles has PCE only 4.02 %. This result is very promising in terms low temperature and thus low cost of anatase TiO2 semiconductor preparation for DSSC application.
机译:通过利用太阳能源作为可再生能源的替代来源开发的一个设备是染料敏化的太阳能电池(DSSC)。该设备在分子水平中使用简单的光合电化学原理工作。在该装置中,二氧化钛(TiO2)的无机氧化物半导体具有从太阳能源的光子能吸收的巨大潜力,尤其是TiO2纳米颗粒结构的形式。该纳米粒子结构预计将提高DSSC的性能,因为该纳米结构的表面积至重量比非常大。在该研究中,已经通过其前体合成TiC2纳米颗粒以及DSSC装置的制造。通过在各种温度下的低水热处理完成纳米晶锐钛矿TiO2的努力,而通过煅烧过程进行结构中的锐钛矿相的结晶度。使用X射线衍射(XRD)和扫描电子显微镜(SEM)进行材料的表征,而通过高精度电流与电压(I-V)曲线分析仪检查DSSC性能。结果表明,纯锐钛矿TiO2纳米颗粒可以在100,125和150℃的低水温下获得,然后在450℃下进行煅烧。通过在150℃下的TiO 2在150℃下合成的光电流 - 电压特性的最佳性能,功率转换效率为4.40%,而标准TiO2纳米颗粒具有仅为4.02%的PCE。该结果在低温方面非常有前途,因此锐钛矿TiO2半导体制剂的低成本用于DSSC应用。

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