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Physical And Optical Properties Of K_2O-TeO_2-WO_3- B_2O_3 Glasses

机译:K_2O-TEO_2-WO_3-B_2O_3眼镜的物理和光学性质

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Tellurium based glasses containing WO3, B2O3 and K2O are investigated through density, glass transition temperature and optical properties. The density and glass transition temperature of the present gasses varies with K2O mole%. From the optical absorption studies, the values of direct optical band gap, indirect optical band gap energy (E_0) and Urbachenergy(ΔE) have been evaluated. The values of E_0 and ΔE vary linearly with K2O mole%. The electronic polarizability of oxide ions, optical basicity and the Yamashita- Kurosawa's interaction parameter have been examined to check the correlation among them and bond character. Based on good correlation among electronicpolarizability of oxide ions, optical basicity and the Yamashita- Kurosawa's interaction parameter, the present K_2O-TeO_2-WO_3-B_(2O3) glasses were classified as normal ionic (basic) oxides.
机译:通过密度,玻璃化转变温度和光学性能研究含有WO3,B2O3和K2O的碲基玻璃。本气体的密度和玻璃化转变温度随K2O摩尔%而变化。从光学吸收研究中,已经评估了直接光带隙,间接光带隙能量(E_0)和urbachEnergy(ΔE)的值。 E_0和ΔE的值与K2O摩尔%线性变化。已经检查了氧化物离子,光学碱度和纱线的相互作用参数的电子极化性以检查它们和粘合性的相关性。基于氧化物离子,光学碱度和纱线的相互作用参数的良好相关性,本发明的K_2O-TEO_2-WO_3-B_(2O3)玻璃被分类为正常离子(碱性)氧化物。

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