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Heterogeneous photo-decolourization of cobaltous phthalocyaninate dye (reactive green dye) catalyzed by ZnO

机译:ZnO催化催化钴酞菁染料(反应性绿色染料)的异质光脱色

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This study focused on the photocatalytic decolourization of cobaltous phthalocyaninate dye (PcCo) from ZnO suspension solution under artificial UV-A light. The results showed that the photo-decolourization process of this dye process was obeyed to pseudo-first order kinetics. Moreover, the optimization results explained that the maximum value of decolourization efficiency of this dye was achieved at the conditions: initial dye concentration 25 mg/L and the initial pH of dye aqueous solution is equal to 11.01. Arrhenius plot obtained at temperatures ranged (287.15-303.15) K, which is equal to 28.995 kJ mol-1. The thermodynamic parameters were calculated also and determined that the photoreaction is endothermic and non-spontaneous.
机译:该研究专注于从人造UV-A光下从ZnO悬浮液中的钴邻酞菁染料(PCO)的光催化脱色。结果表明,这种染料过程的光脱色过程遵守伪第一阶动力学。此外,优化结果说明了在条件下实现了该染料的脱色效率的最大值:初始染料浓度25mg / L,染料水溶液的初始pH值等于11.01。在温度下获得的Arhenius图(287.15-303.15)k,其等于28.995 kJ mol-1。计算热力学参数并确定光反应是吸热和非自发性的。

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