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Construction of one new coordination polymers based on 5-(pyridin-4-yl)isophthalic acid acid ligands: synthesis, crystal structures and magnetism

机译:基于5-(吡啶-4-基)间苯二甲酸配体的一种新配位聚合物的构建:合成,晶体结构和磁

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摘要

One new coordination polymer, namely, {[Co(L1)H)_2O]·H_2O}_n 1 [L1=5-(pyridin-4-yl)isophthalic acid], has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, X-ray diffraction and thermogravimetric analysis. In compound 1, three oxygen atoms and one nitrogen atoms of the ligand, a T-shaped linker, coordinate to four metals centers to form an infinite double-layer structures, exhibiting extended 3D supramolecular network via O-H…O hydrogen bonding interactions.
机译:一种新的配位聚合物,即([CO(L1)H)_2O]·H_2O} _N1 [L1 = 5-(吡啶-4-基)脱苯二甲酸],在水热条件下已经合成,并通过元素分析表征,红外光谱,X射线衍射和热重分析。在化合物1,三个氧原子和配体的一个氮原子中,T形接头,与四个金属中心坐标以形成无限的双层结构,通过O-H ... o氢键相互作用表现出延伸的3D超分子网络。

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