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Data Reduction in Size-Exclusion Chromatography with Molar Mass Sensitive Detectors

机译：具有摩尔质量敏感探测器尺寸排除色谱的数据减少

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A comprehensive analysis of recent improvements in data reduction in triple-detector SEC is presented. Using direct measurements of a sample's hydrodynamic volume across the entire polymer distribution, different sources of non-ideality of size-exclusion separation can be analyzed as well as their effect on accuracy of the calculated molar mass distribution and polymer solution properties. Elimination of concentration detector traces may significantly improve the quantitation of polymers with long high-molar-mass tails, e.g., caused by long-chain branches. Novel approaches to model fitting of calibration and structural curves describing the relations between polymers' structural parameters are discussed in detail. The characterization of an ethylene-methyl acrylate copolymer illustrates the quantitative approaches.

机译：介绍了近期三维探测器SEC数据减少改进的全面分析。在整个聚合物分布上使用样品的流体动力学体积的直接测量，可以分析不同尺寸排除分离的不同理想源，以及它们对计算的摩尔质量分布和聚合物溶液性能的精度的影响。消除浓度检测器迹线可以显着提高具有长高摩尔质量尾部的聚合物的定量，例如由长链分支引起的。详细讨论了描述了描述聚合物结构参数关系的校准和结构曲线模型拟合的新方法。乙烯 - 甲基丙烯酸酯共聚物的表征示出了定量方法。

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《American Chemical Society》|2005年||共21页
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作者
Yefim Brun;
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中图分类色层吸附分析（层析法）;
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1. Estimation of band broadening in size-exclusion chromatography. I. A method based on analyzing narrow standards with a molar mass-sensitive detector [J] . Yossen MM, Vega JR, Meira GR Journal of chromatography, A: Including electrophoresis and other separation methods . 2006,第1a2期

机译：尺寸排阻色谱中谱带展宽的估计。一，一种基于摩尔质量敏感检测器分析窄标准物的方法
2. Determination of the absolute molar mass of acetylated eucalyptus kraft lignin by two types of size-exclusion chromatography combined with multi-angle laser light-scattering detectors [J] . Wang Linping, Uraki Yasumitsu, Koda Keiichi, Holzforschung . 2019,第4期

机译：两种尺寸排阻色谱-多角度激光散射检测器测定乙酰化桉树牛皮纸浆木质素的绝对摩尔质量
3. Determination of the absolute molar mass of acetylated eucalyptus kraft lignin by two types of size-exclusion chromatography combined with multi-angle laser light-scattering detectors [J] . Wang Linping, Uraki Yasumitsu, Koda Keiichi, Holzforschung . 2019,第4期

机译：两种尺寸排除色谱法与多角激光散射检测器相结合的乙酰化桉树绝对摩尔质量的测定
4. Data Reduction in Size-Exclusion Chromatography with Molar Mass Sensitive Detectors [C] . Yefim Brun American Chemical Society . 2005

机译：具有摩尔质量敏感探测器尺寸排除色谱的数据减少
5. Multi-detector hydrodynamic chromatography: Particle characterization and ultra-high molar mass polymer analysis. [D] . Brewer, Amandaa Kimberly. 2010

机译：多检测器流体动力学色谱：颗粒表征和超高摩尔质量的聚合物分析。
6. Analytical method validation for terbutryn using gas chromatography/ion trap gas chromatography/mass selective detector and liquid chromatography/triple quadrupole mass spectrometers [O] . Hae Won Jang, Jangho Lee, Hyunwook Choi, 2018

机译：使用气相色谱/离子阱气相色谱/质量选择检测器和液相色谱/三重四极杆质谱仪对叔丁草进行分析方法验证
7. Analysis of Pesticides Residues in Fresh Produce Using Buffered Acetonitrile Extraction and Aminopropyl Cleanup with Gas Chromatography/Triple Quadrupole Mass Spectrometry, Liquid Chromatography/Triple Quadrupole Mass Spectrometry, Gas Chromatography/Ion Trap Detector Mass Spectrometry, and GC with a Halogen-Specific Detector [O] . Amy N Brown, Jo Marie Cook, Walter T Hammack, 2011

机译：使用缓冲乙腈萃取和氨基丙基清扫氨基丙基含有气相色谱/三重四极杆质谱，液相色谱/三重四极孔质谱法，气相色谱/离子捕集器质谱法，气相色谱/离子捕集器质谱法，含有卤素特异性探测器的农药残留物

Data Reduction in Size-Exclusion Chromatography with Molar Mass Sensitive Detectors

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