Studies of Electrolyte Oxidation Using In-situ Infrared Reflection Absorption Spectroscopy

机译：使用原位红外反射吸收光谱研究电解质氧化

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The typical operational potential of a lithium battery is between 0 and 5 V,the range of which is beyond the thermodynamic range of most organic solvents it employed.Solvents,therefore,can be reduced and/or oxidized at the negative and positive electrodes during the battery charging process.The decomposition mechanisms are complicated and no clear understanding has been reached despite a substantial research effort.Utilizing the tools of computational quantum chemistry in combination with improved in-situ experimental techniques such as Infrared Reflection Absorption Spectroscopy (IRRAS) and Atomic Force Microscopy (AFM) we were able to shed some light on the solvent reduction and oxidation mechanisms.

机译：锂电池的典型操作电位在0和5V之间，其范围超出其所用的大多数有机溶剂的热力学范围。因此，可以在负极和正电极处减少和/或氧化电池充电过程。尽管有实质性的研究，但仍然没有明确的理解，尽管有实质性的研究，但甚至与改善的原位实验技术（例如红外反射吸收光谱（ANRAR）和原子力）组合的计算量子化学的工具显微镜（AFM）我们能够在溶剂还原和氧化机制上阐明一些光。

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《The Meeting of the Electrochemical Society》|2002年||共1页
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XueRong Zhang; Philip N.Ross;
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2. In-situ Observation of Electrochemical Etching Processes of a Silicon SurfaceUsing Infrared Absorption Spectroscopy in Multiple Internal Reflection GeometryIn-situ Observation of Electrochemical Etching Processes of a Silicon SurfaceUsing Infrared Ab [J] . Yasuo KIMURA, Yoshinobu HOSOI, Hisao ISHII 表面科学 . 2004,第2期

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4. Studies of Electrolyte Oxidation Using In-situ Infrared Reflection Absorption Spectroscopy [C] . XueRong Zhang, Philip N.Ross The Meeting of the Electrochemical Society . 2002

机译：使用原位红外反射吸收光谱研究电解质氧化
5. A study of polymer tertiary structure in Langmuir monolayer films of poly(dimethyl siloxane) by time-of-flight secondary ion mass spectrometry, reflection-absorption Fourier transform infrared spectroscopy and high-resolution electron energy loss spectroscopy. [D] . Piwowar, Alan M. 2007

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机译：原位偏振调制FT IRRas（傅里叶变换红外反射吸收光谱法）研究金/氰化物溶液间期

Studies of Electrolyte Oxidation Using In-situ Infrared Reflection Absorption Spectroscopy

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