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首页> 外文会议>International Conference on Advanced Materials Processing Technologies >THERMAL PROPERTIES AND INTERACTIONS IN BLENDS OF POLY(ε-CAPROLACTONE) WITH UNSATURATED POLYESTER RESINS
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THERMAL PROPERTIES AND INTERACTIONS IN BLENDS OF POLY(ε-CAPROLACTONE) WITH UNSATURATED POLYESTER RESINS

机译：具有不饱和聚酯树脂的聚（ε-己内酮）混合物的热性质和相互作用

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Blends of two linear unsaturated polyester (UP, commercially named AL-100 and 6603) with poly(ε-caprolactone ) (PCL) were prepared by the casting method. Differential scanning calorimetry has been used to study the miscibility, melting behaviour and crystallinity of 6603+PCL and AL100+PCL blends. Two different heat treatments, (method 1 and method 2), were carried out, in both systems. Only by following method 2 a crystallization temperature (Tc) was selected before monitoring the glass transition and melting behaviour of the blends. When samples were scanned under method 1, a unique T{sub}g intermediate between the (T{sub}g)'s of the pure polymers in all the blends studied was found. It indicates that the PCL is miscible with both unsaturated resins in the whole composition range. Nevertheless, when samples were scanned following method 2 the T{sub}g - composition dependence exhibited an asymmetric behaviour that could indicate a certain lack of homogeneity in the blends at intermediate compositions.
机译：通过铸造方法制备具有聚（ε-己内酯）（PCL）的两个线性不饱和聚酯（上升，商业名称AL-100和6603）的混合物。差分扫描量热法已用于研究6603 + PCL和Al100 + PCL共混物的混溶性，熔化行为和结晶度。在两个系统中进行两种不同的热处理，（方法1和方法2）。只有通过以下方法2，在监测混合物的玻璃化转变和熔化行为之前选择结晶温度（Tc）。当在方法1下扫描样品时，发现在研究的所有共混物中的纯聚合物的（T {Sub} G）之间的唯一T {Sub} G中间。表明PCL与整个组成范围内的两个不饱和树脂混溶。然而，当扫描样品后，扫描样品2时，T {亚} G - 组合物依赖性表现出不对称的行为，其可以表明中间组合物中的共混物中的某种缺乏均匀性。

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