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Syndiospecific synthesis of copolymers of styrene with p-alkyl-substituted styrenes using monocyclopentadienyl-type titanium catalysts

机译：单环戊二烯基型钛催化剂的对烷基取代苯乙烯与p-烷基取代苯乙烯共聚物的合成

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Since Ishihara et al.first synthesized syndiotactic polystyrene (PS) using transition-metal catalysts in 1986,syndiotactic PS has been recognized as a new crystalline engineering material applicable for molding goods.Although syndiotactic PS shows good thermal and mechanical properties,it has some inherent drawbacks such as brittleness and a low thermal decomposition temperature (approx300 degC).

机译：由于ISHIHARA等人在1986年使用过渡金属催化剂的合成的长立 - 催化剂（PS），Syndiotic PS已被认为是一种适用于模塑产品的新型晶体工程材料。虽然Syndiotic PS显示出良好的热和机械性能，但它具有一些固有的诸如脆性和低热分解温度（大约300℃）的缺点。

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《PMSE Symposia》|2001年||共2页
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Roderic P.Quirk; Myung-Ahn Ok;
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中图分类合成树脂与塑料工业;
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专利

1. Tuning the active species from syndiospecific styrene polymerisation to ethylene/styrene copolymerisation by (aryloxo)(cyclopentadienyl)titanium complexes-MAO catalysts [J] . Zhang H, Byun DJ, Nomura K Dalton transactions: An international journal of inorganic chemistry . 2007,第18期

机译：通过（芳基氧代）（环戊二烯基）钛配合物-MAO催化剂将活性种从间规苯乙烯聚合反应转化为乙烯/苯乙烯共聚合反应
2. Syndiospecific Synthesis of Longer p-ft-Alkyl-Substituted Polystyrenes Using Monocyclopentadienyl-Type Titanium Catalysts [J] . Roderic P.Quirk, Myung-Ahn Ok Macromolecules . 2004,第11期

机译：单环戊二烯基型钛催化剂间位合成长对位烷基取代的聚苯乙烯
3. Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene-Ethylene Copolymerization: Unprecedented Incorporation of Syndiotactic Styrene-Styrene Sequences in Styrene-Ethylene Copolymers [J] . Yunjie Luo, Jens Baldamus, Zhaomin Hou Journal of the American Chemical Society . 2004,第43期

机译：Half半茂金属催化的间二苯乙烯聚合和苯乙烯-乙烯共聚：苯乙烯-乙烯共聚物中间同苯乙烯-苯乙烯序列的前所未有的结合
4. Syndiospecific synthesis of copolymers of styrene with p-alkyl-substituted styrenes using monocyclopentadienyl-type titanium catalysts [C] . Roderic P.Quirk, Myung-Ahn Ok PMSE Symposia . 2001

机译：单环戊二烯基型钛催化剂的对烷基取代苯乙烯与p-烷基取代苯乙烯共聚物的合成
5. Mechanistic investigations of titanium-mediated syndiospecific styrene polymerizations. [D] . Mahanthappa, Mahesh Kalyana. 2003

机译：钛介导的间同苯乙烯聚合的机理研究。
6. Supramolecular Networks from Block Copolymers Based on Styrene and Isoprene Using Hydrogen Bonding Motifs—Part 1: Synthesis and Characterization [O] . Elaine Rahmstorf, Volker Abetz 2018

机译：氢键基团的基于苯乙烯和异戊二烯的嵌段共聚物的超分子网络—第1部分：合成和表征
7. Multiple Injection Method for Bulk Syndiospecific Polymerization of Styrene with Homogeneous Metallocene Catalyst [O] . Jin-Heong Yim, Young-Gon Son 2010

机译：用均质茂金属催化剂甲烯本体Syndiophicific聚合的多注射方法
8. Synthesis and SAXS Characterization of Sulfonated Styrene- Ethylene/Propylene-Styrene Triblock Copolymers [R] . Mather, B. D. , Beyer, F. L. , Long, T. E. 2006

机译：磺化苯乙烯 - 乙烯/丙烯 - 苯乙烯三嵌段共聚物的合成及saXs表征

Syndiospecific synthesis of copolymers of styrene with p-alkyl-substituted styrenes using monocyclopentadienyl-type titanium catalysts

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