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Synthesis of AB2-Type Star-Shaped Ethylene-Styrene Block Copolymers by Combining Pd-Diimine Catalyzed Ethylene Living Polymerization with ATRP

机译：通过将Pd-二亚胺催化乙烯活化聚合与ATRP合并通过组合AB2型星形乙烯 - 苯乙烯嵌段共聚物的合成

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Developing functionalized polyolefins is an important and challenging theme in polyolefins research and development. The presence of functional groups on the non-polar polyolefin chains imparts functionalized polyolefins with enhanced materials properties, such as toughness, barrier properties, surface properties, miscibility with other polar polymers, etc. Owing to the highly oxophilic nature of most catalyst systems for olefin coordination polymerization, the commercial production of functionalized polyethylenes is generally restricted to ethylene radical copolymerization with polar functional comonomers. Though the developments in low-oxophilic late-transition-metal Pd- diimine catalysts have enabled the direct olefin copolymerization with functional comonomers, the comonomer incorporation is usually low and the comonomer types are rather limited.

机译：开发官能化聚烯烃是聚烯烃研究和开发中的重要且挑战性的主题。非极性聚烯烃链上的官能团的存在赋予官能化的聚烯烃，其具有增强的材料性质，例如韧性，阻隔性，表面性质，与其他极性聚合物的混溶性。由于烯烃的大多数催化剂体系的高抗乳化性质配位聚合，官能化聚乙烯的商业生产通常限于与极性功能性共聚单体的乙烯自由基共聚合。虽然低苯酚的后过渡金属PD-二亚胺催化剂的发展使得具有功能性共聚单体的直接烯烃共聚，但共聚单体掺入通常是低的，并且共聚单体类型相当有限。

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《PMSE Symposia》|2007年||共2页
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Xiubo Tang; Zhibin Ye;
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中图分类高分子化学（高聚物）;
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1. Synthesis of block copolymers of ethylene with styrene and n-butyl acrylate via a tandem strategy combining ethylene "Living" polymerization catalyzed by a functionalized Pd-diimine catalyst with atom transfer radical polymerization [J] . Zhang K, Ye Z, Subramanian R Macromolecules . 2008,第3期

机译：通过串联策略合成乙烯与苯乙烯和丙烯酸正丁酯的嵌段共聚物，该策略将官能化的Pd-二亚胺催化剂催化的乙烯“活”聚合与原子转移自由基聚合相结合
2. Synthesis of star-shaped copolymers with methyl methacrylate and n-butyl methacrylate by metal-catalyzed living radical polymerization: Block and random copolymer arms and microgel cores [J] . Baek KY., Kamigaito M., Sawamoto M. Journal of Polymer Science, Part A. Polymer Chemistry . 2002,第5期

机译：金属催化的活性自由基聚合合成甲基丙烯酸甲酯和甲基丙烯酸正丁酯的星形共聚物：嵌段和无规共聚物臂和微凝胶核
3. Enzyme mimetic-catalyzed ATRP and its application in block copolymer synthesis combined with enzymatic ring-opening polymerization [J] . Zhou Hang, Jiang Wei, An Ni, RSC Advances . 2015,第53期

机译：酶模拟催化的ATRP及其在嵌段共聚物合成中的应用及酶促开环聚合
4. Synthesis of AB2-Type Star-Shaped Ethylene-Styrene Block Copolymers by Combining Pd-Diimine Catalyzed Ethylene Living Polymerization with ATRP [C] . Xiubo Tang, Zhibin Ye PMSE Symposia . 2007

机译：通过将Pd-二亚胺催化乙烯活化聚合与ATRP合并通过组合AB2型星形乙烯 - 苯乙烯嵌段共聚物的合成
5. Controlled/living polymerizations. A. Synthesis of block copolymers with bicyclic acetals by cationic ring opening polymerization. B. Synthesis and study of tetradentate ligands coordinated to copper(I) and copper(II) for use as ATRP catalysts. [D] . Troeltzsch, Christina. 2003

机译：受控/活性聚合。 A.通过阳离子开环聚合反应与双环缩醛合成嵌段共聚物。 B.用作ATRP催化剂的与铜（I）和铜（II）配位的四齿配体的合成和研究。
6. Synthesis Self-Assembly and Drug Delivery Characteristicsof Poly(methyl caprolactone-co-caprolactone)-b-poly(ethylene oxide) Copolymers with Variable Compositionsof Hydrophobic Blocks: Combining Chemistry and Microfluidic Processingfor Polymeric Nanomedicines [O] . Zheqi Xu, Changhai Lu, Carly Lindenberger, 2017

机译：合成自组装和药物输送特性可变组成的聚（甲基己内酯-共己内酯）-b-聚环氧乙烷共聚物疏水性嵌段的组合：化学与微流体加工相结合用于高分子纳米药物
7. Straightforward Synthesis of Conjugated Block Copolymers by Controlled SuzukiMiyaura Cross-Coupling Polymerization Combined with ATRP [O] . -1

机译：通过控制的舒苏霉素交叉偶联聚合结合ATRP，直接合成共轭嵌段共聚物
8. Synthesis of Side Chain Liquid Crystal Polymers by Living Ring Opening Metathesis Polymerization. 4. Synthesis of Amorphous and Side Chain Liquid Crystal AB Block Copolymers. [R] . Komiya, Z., Pugh, C., Schrock, R. R. 1992

机译：活环开环易位聚合法合成侧链液晶聚合物。 4.非晶和侧链液晶aB嵌段共聚物的合成。

Synthesis of AB2-Type Star-Shaped Ethylene-Styrene Block Copolymers by Combining Pd-Diimine Catalyzed Ethylene Living Polymerization with ATRP

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