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Novel Biocomposites from Polylactide (PLA) and Bamboo Fibers

机译:来自聚乳糖(PLA)和竹纤维的新型生物复合材料

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Biodegradable polymers such as polylactide (PLA) have been widely studied during the past decade. PLA has better mechanical properties than polypropylene (PP). However, in some cases, PLA cannot be used independently for the adjustment of toughness. A relatively easy way to improve the mechanical properties of a polymer is the addition of fibers or filler materials. Bamboo is an abundant natural resource in Asia and South America, and its overall mechanical properties are comparable to or surpass those of wood. It is necessary to develop a practical process for fabricating bamboo fiber reinforced composites. The present study evaluates the mechanical and thermal performances of the pre-treated bamboo reinforced biocomposites. In order to enhance the behavior of these composites, bamboo fibers have been treated with sodium hydroxide and a silane coupling agent. 3- Aminopropyltriethoxysilane (APS) was used as a surface modifying coupling agent for bamboo fibers, because of the ability of APS to bond to PLA, as suggested by Dupraz et al.. During the surface treatment, APS hydrolyzes and the resultant silanol groups can bond with the bamboo fiber surface. Amine groups from APS can form hydrogen bonds to COO-sites on the hydrolyzed PLA backbone. The aim of this study is to investigate the influence of fiber surface treatment on the mechanical and thermal-mechanical properties of the bamboo fiber reinforced PLA composites. Bamboo fiber reinforced PP composites were also processed in order to compare their properties with PLA composites.
机译:在过去十年中,可生物降解的聚合物如聚物(PLA)已被广泛研究。 PLA具有比聚丙烯(PP)更好的机械性能。但是,在某些情况下,PLA不能独立使用,以调整韧性。改善聚合物的机械性能的相对简单的方法是添加纤维或填充材料。竹子是亚洲和南美的丰富自然资源,其整体机械性能与木材相当或超越木材。有必要开发一种制造竹纤维增强复合材料的实用方法。本研究评估了预处理的竹增强生物复合材料的机械和热性能。为了增强这些复合材料的行为,已用氢氧化钠和硅烷偶联剂处理竹纤维。 3-氨基丙基三乙氧基硅烷(APS)用作竹纤维的表面改性偶联剂,因为APS与PLA键合的能力,如Dupraz等人在表面处理期间,APS水解和所得硅烷醇组可以与竹纤维表面粘合。来自AP的胺基团可以将氢键与水解的PLA骨架上的Coo-位点形成。本研究的目的是探讨纤维表面处理对竹纤维增强PLA复合材料的机械和热机械性能的影响。还处理竹纤维增强PP复合材料,以便将它们的性质与PLA复合材料进行比较。

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