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Polyisobutenyl Carboxylic Acid: A New Versatile Functional Polymer and Its Derivatizations by Simple Organic Reactions

机译:聚异丁烯羧酸:通过简单的有机反应的新的多种功能性聚合物及其衍生化

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One of the major objectives of polymer material scientists is to create new materials with desired, often multiple properties, which determine the applicability of different components in one complex structure. The connection between these substances can be physical, chemical or both, depending on their planned application. For example, supramolecular gels were obtained by the use of polyisobutylene (PIB) in which the end groups were chemically modified in order to create strong hydrogen bonding interactions to a corresponding polymer, leading to the formation of weak gels [1]. Polyisobutylene has exceptional advantageous physical, chemical and biological properties. Accordingly, PIB has a variety of applications in both academia and industry. Due to its fully saturated hydrocarbon backbone, it has low reactivity, but this fact also prevents the simple attachment of PIB to other reagents or materials. Numerous studies have already dealt with the functionalization and further modification of PIB chain ends in order to produce new materials with improved properties [2-6]. However, such functionalizations usually require special reactions, reagents and conditions.
机译:聚合物材料科学家的主要目标之一是创造具有所需的新材料,通常是多种性质,该性能决定了不同组分在一种复杂结构中的适用性。根据其计划的应用,这些物质之间的连接可以是物理,化学或两者。例如,通过使用聚异丁烯(PIB)获得超分子凝胶,其中结束基团化学改性以形成与相应聚合物的强氢键相互作用,导致薄凝胶的形成[1]。聚异丁烯具有出色的有利物理,化学和生物学性质。因此,PIB在学术界和工业中具有各种应用。由于其完全饱和的烃骨架,它具有低的反应性,但这事实也可以防止PIB简单地附着到其他试剂或材料。许多研究已经处理了官能化,进一步改性Pib链末端,以产生具有改进性质的新材料[2-6]。然而,这种官能化通常需要特殊反应,试剂和条件。

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