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Preparation and Characterization of Polyimide/Organo-Modified Graphene Oxide Nanocomposites

机译:聚酰亚胺/有机改性石墨烯纳米复合材料的制备与表征

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A Graphene, a two-dimensional lattice of sp2-bonded carbon atoms, is one of the most exciting materials for intense research since 2004. The unique electronic properties of graphene sheets with a high specific surface area are promising for potential applications in the fabrication of various electronic devices, such as field-effect transistors, ultrasensitive sensors, and transparent electrodes, as well as novel nanocomposite materials. A great deal of effort has been made to prepare graphene nanosheets as thin as possible and homogeneously disperse them in the polymer matrix in order to obtain graphene-polymer nanocomposites with excellent mechanical and conducting properties. A good and facile approach is the molecular level dispersion of graphene into the polymer matrix via an environmentally benign modification process, even though the concentration of graphene oxide is low in the system. Among the various methods that are available for the preparation of nanocomposites, Torkelson et al employed a solid-state shear pulverization pathway that enhances the chemical and thermal properties of the product polymer-graphene nanocomposites. This method effectively synthesizes well-dispersed nanocomposites with major improvements in the mechanical properties at very low weight percentages for the polymer dispersion. Graphene-based polymer nanocomposites are very promising candidates for new high-performance materials, and therefore, graphene has attracted more attention as a potential reinforcement material in polymer matrixes. In this work, polyimide/GO nanocomposites were prepared and characterized.
机译:石墨烯是自2004年以来的最令人兴奋的研究中最令人兴奋的研究之一。具有高比表面积的石墨烯片的独特电子特性是对制造中的潜在应用的唯一应用。各种电子设备,例如场效应晶体管,超声传感器和透明电极,以及新型纳米复合材料。已经做出了大量的努力,以制备石墨烯纳米片,尽可能薄,并均匀地将它们分散在聚合物基质中,以获得具有优异的机械和导电性能的石墨烯 - 聚合物纳米复合材料。良好的和容易的方法是石墨烯通过环境良性修饰方法将石墨烯分散到聚合物基质中的分子水平分散,即使系统中的氧化石墨烯的浓度低。在可用于制备纳米复合材料的各种方法中,Torkelson等人使用固态剪切粉碎途径,可增强产物聚合物 - 石墨烯纳米复合材料的化学和热性质。该方法有效地合成了井分散的纳米复合材料,在极低的重量百分比下为聚合物分散体的重量百分比主要改善。基于石墨烯的聚合物纳米复合材料对于新的高性能材料非常有前途的候选者,因此,石墨烯已经吸引了聚合物基质中潜在的增强材料。在这项工作中,制备聚酰亚胺/去纳米复合材料并表征。

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