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LUMINESCENT PROPERTIES OF Li_2B_4O_7 (LTB) POLYCRYSTALS AT THE DEVIATION FROM STOICHIOMETRY

机译:Li_2b_4o_7(LTB)多晶的发光特性在化学计量偏差下的偏差

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An analysis of literature data, shows that the more widespread use of polycrystalline Li_2B_4O_7 (LTB) based dosimetric materials is restricted by irreproducibility of the parameters of samples from different technological batches. In our opinion, one of the most essential causes of this irreproducibility is a deviation from the stoichiometric Li_2B_4O_7 composition. This may arise when during synthesis, due to a high hygroscopicity of the initial substances, weighing errors and incongruent evaporation of components during synthesis. However, no studies of the influence of this deviation on the LTB luminescent properties have yet been carried out. In this work, the influence of deviations from stoichiometry on the X-ray luminescent (XL) spectra, and on the intensities and temperatures of maxima in the thermostimulated luminescence (TSL) curves, has been studied.
机译:文献数据的分析表明,多晶Li_2b_4O_7(LTB)基于剂量的较为广泛的使用受到来自不同技术批次的样本参数的IrreoRoducibituce的限制。在我们看来,这种IRRE再生产性的最重要原因之一是与化学计量LI_2B_4O_7组成的偏差。在合成期间,这可能是由于初始物质的高湿性,称重误差和合成期间组分的不一致蒸发。然而,没有对这种偏差对LTB发光特性的影响的研究已经进行。在这项工作中,研究了偏离化学计量对X射线发光(XL)光谱的影响以及在热刺激发光(TSL)曲线中最大值的强度和温度的影响。

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