Characterization of gas-phase HCI-H_2O clusters using pulsed infrared cavity ringdown spectroscopy

机译：使用脉冲红外腔振荡光谱法的气相HCI-H_2O簇的表征

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Using the Berkeley medium-resolution pulsed cavity ringdown spectrometer we have observed the HC1 stretch spectrum of the HC1-H2O dimer and DC1 stretch mode of the completely deuterated analog. The shifts from the free HC1 stretch are consistent with theory and Ar matrix isolation work. Rotational structure was obtained for the deuterated cluster and spectroscopic constants for both chlorine isotopomers determined. Cluster number densities were determined to be slightly lower than found for the pure water dimer under similar conditions.

机译：使用伯克利中分辨率脉冲腔振荡仪，我们观察到HC1-H2O二聚体的HC1拉伸光谱和完全氘代的模拟的DC1拉伸模式。自由HC1伸展的换档与理论和ar矩阵隔离工作一致。为氘代簇和测定的两种氯同种甲酰基的光谱常数获得旋转结构。确定簇数密度略低于在类似条件下为纯水二聚体的略低。

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《Conference on methods for ultrasensitive detection》|2002年||共8页
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Richard J. Saykally; Fredrik Hellberg; Ross J. Stickland; Alex J. Huneycutt;
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中图分类真空测试技术;
关键词
cavity ringdown; HClH_2O; acid clusters; CRLAS;

机译：腔旋转;HCLH_2O;酸簇;CRLAS;

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专利

1. High resolution pulsed infrared cavity ringdown spectroscopy: Application to laser ablated carbon clusters [J] . Casaes R., Provencal R., Paul J., The Journal of Chemical Physics . 2002,第15期

机译：高分辨率脉冲红外腔衰荡光谱：在激光烧蚀碳簇中的应用
2. High resolution pulsed infrared cavity ringdown spectroscopy: Application to laser ablated carbon clusters [J] . Casaes R., Provencal R., Paul J., The Journal of Chemical Physics . 2002,第15期

机译：高分辨率脉冲红外腔衰荡光谱：在激光烧蚀碳簇中的应用
3. Solvated structures of pyrrole-acetonitrile binary clusters studied by infrared cavity ringdown spectroscopy [J] . Iwamoto J.-I., Matsumoto Y., Honma K. Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature . 2013,第Null期

机译：红外腔衰荡光谱研究吡咯-乙腈二元簇的溶剂化结构
4. Characterization of gas-phase HCI-H_2O clusters using pulsed infrared cavity ringdown spectroscopy [C] . Alex J. Huneycutt, Ross J. Stickland, Fredrik Hellberg, Conference on Methods for Ultrasensitive Detection Ⅱ Jan 21-22, 2002, San Jose, USA . 2002

机译：脉冲红外腔衰荡光谱法表征气相HCI-H_2O团簇
5. Pulsed infrared cavity ringdown laser absorption spectroscopy. [D] . Casaes, Raphael Nunes. 2003

机译：脉冲红外腔振铃激光吸收光谱。
6. Gas-Phase Infrared Ion Spectroscopy Characterizationof Cu(II/I)Cyclam and Cu(II/I)22′-BipyridineRedox Pairs [O] . MuslehUddin Munshi, Jonathan Martens, Giel Berden, -1

机译：气相红外光谱表征（II / I）Cyclam和Cu（II / I）22-联吡啶的合成氧化还原对
7. Characterization of gas-phase HCl-H2O clusters using pulsed infrared cavity ringdown spectroscopy [O] . Alex J. Huneycutt*a, Ross J. Stickl, Fredrik Hellbergc, 2015

机译：用脉冲红外腔衰荡光谱表征气相HCl-H2O簇
8. Infrared Cavity Ringdown Spectroscopy of Hydrocarbon Ions and Clusters in Fast Ion Beams [R] . Saykally, R. J. 2004

机译：快离子束中烃离子和团簇的红外腔衰荡光谱

Characterization of gas-phase HCI-H_2O clusters using pulsed infrared cavity ringdown spectroscopy

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