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Recovery of Acetic Acid from Antibiotics Industrial Effluents Pervaporation with a Combination of Hydrophobic Ionic Liquids

机译:用抗生素工业污水渗透到疏水离子液体的组合回收乙酸

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The present work is proposed to evaluate the potential of using an integrated pervaporation process to separate water-rich acetic acid mixtures. This integrated pervaporation process based on a simple PDMS membrane with a combination ofhydrophobic ionic liquid which are molten comprised of an array of heterocyclic cations and various anions. A hydrophobic ionic liquid phase is introduced as the third phase between the water phase and the solid PDMS membrane phase for improving the selectivity and mass transfer of acetic acid from its aqueous matrix. The feed temperature as an important operation condition was investigated in this work. The primary results show that the ionic liquid as an extractant prior to the pervaporation process is favorable for improving significantly the selectivity and permeating flux of acetic compared with the PDMS pervaporation process. This performance could be attributed to the acetic acid concentrated in ionic liquid phase prior to the permeate by pervaporation. A sample of an antibiotic pharmaceutical effluent was investigated using the above integrated pervaporation process, and the result suggests that this integrated pervaporation process can be developed to an industrial scale for recover acetic acids from water-rich effluent.
机译:提出了本作当前的作品,评价使用综合渗透流程来分离富含水性乙酸混合物的潜力。这种基于简单的PDMS膜的整合渗透蒸发方法,其具有氢硼离子液体的组合,其熔融包括杂环阳离子和各种阴离子的阵列。疏水离子液相作为水相和固体PDMS膜相之间的第三相引入,以改善乙酸的含水基质的选择性和传质。在这项工作中研究了作为重要操作条件的饲料温度。主要结果表明,离子液体作为渗透过程前的萃取剂有利于显着改善与PDMS渗透流程相比的乙酸的选择性和渗透通量。通过渗透渗透剂在渗透物之前,这种性能可能归因于浓缩的乙酸浓缩的离子液相。使用上述整合的渗透散流程研究了抗生素药物流出物的样品,结果表明,这种集成的渗透流程可以开发成工业规模,以回收来自富含水流的流出物的醋酸。

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