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Development of electroless deposition bath for Pt-Ru system and characterization for Pt- Ru bimetallic catalysts

机译:PT-Ru系统化学沉积浴的开发及Pt-Ru双金属催化剂的表征

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Bimetallic catalysts have replaced monometallic catalysts for a wide range of catalytic applications. Bimetallic catalysts often exhibit enhanced selectivity, stability, and/or activity relative to their corresponding monometallic components. Many different methodologies are used for bimetallic catalysts preparation [1]. However, the typical methods of co-impregnation and successive impregnation have poor control of metalmetal interaction and surface composition. Electroless Deposition (ED) has been used for the preparation of true bimetallic catalysts with controlled, bimetallic surface compositions [2, 3]. We have recently studied platinum-ruthenium bimetallic catalysts that are widely used in fuel cells and bio-mass conversion [4]. My research has focused on the preparation and characterization of both platinum deposited on carbon-supported ruthenium catalysts (Ru@Pt/C) as well as Ru deposited on carbon-supported platinum catalysts (Pt@Ru/C).
机译:双金属催化剂已更换单金属催化剂以进行各种催化剂应用。双金属催化剂通常表现出相对于它们相应的单金属组分的增强的选择性,稳定性和/或活性。许多不同的方法用于双金属催化剂制剂[1]。然而,典型的共浸渍和连续浸渍的方法具有较差的金属相互作用和表面组成。化学沉积(ED)已用于制备具有受控的双金属表面组合物[2,3]的真正双金属催化剂。我们最近研究了广泛应用于燃料电池和生物质量转化的铂 - 钌双金属催化剂[4]。我的研究专注于沉积在碳负载的钌催化剂(Ru @ Pt / c)上的铂的制备和表征,以及沉积在碳负载铂催化剂上的Ru(Pt / ru / c)。

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