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Performance of a Dispersive Analyzer for Anomalous Scattering Measurements of Amorphous Materials

机译:用于非晶材料的异常散射测量的分散分析仪的性能

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The partial pair distribution function (PPDF) of an amorphous material is the local environment of an element in the solid. For a two-component system, such as MoGe3, there are three PPDFs: Mo-Mo, Ge-Ge, and Mo-Ge. The PPDF can be derived from anomalous scattering measurements of the material, in this case collecting data near both the Mo and Ge K-absorption edges. Successful derivation of the PPDFs requires the removal of a number of error signals from the x-rays scattered from the sample. In addition to the elastically scattered light, there are both resonant Raman and Compton scattering. Although the resonant Raman Kα signal can be resolved using a solid-state detector, the resonant Raman Kβ and Compton signals cannot. We have developed a variable focal length graphite analyzer which disperses these signals onto a position-sensitive detector. At each scattering angle, a spectrum of the scattered energies is recorded. These spectra are then deconvolved and the elastic signal is integrated. In this paper we present the design and implementation of the analyzer, discussing error sources such as focusing and mechanical compliance.
机译:非晶材料的部分对分布功能(PPDF)是固体中元素的局部环境。对于双组分系统,例如MOGE3,有三种PPDFS:MO-MO,GE-GE和MO-GE。 PPDF可以从材料的异常散射测量导出,在这种情况下,收集Mo和Ge K吸收边缘附近的数据。 PPDF的成功推导要求从样本散射的X射线中删除许多误差信号。除了弹性散射的光线之外,还有谐振拉曼和康普顿散射。尽管可以使用固态检测器来解析谐振拉曼Kα信号,但是谐振拉曼Kβ和COPON信号不能解决。我们开发了一种可变焦距石墨分析仪,将这些信号分散到位置敏感的检测器上。在每个散射角度,记录散射能量的光谱。然后将这些光谱解码,并集成弹性信号。在本文中,我们介绍了分析仪的设计和实现,讨论了重点和机械顺应性等误差来源。

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