Bis(benzimidazole)amine Vanadium Catalysts for Olefin Polymerization and Copolymerization:Thermally Robust, Single-Site Catalysts Activated by Simple Alkylaluminum Reagents

机译：BIS（苯并咪唑）胺钒催化剂用于烯烃聚合和共聚：通过简单的烷基铝试剂激活的热稳健，单现场催化剂

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The past 20 years have seen quite remarkable advances in single-site catalyst technology for the production of polyolefins.1-3 Facilitated by the serendipitous discovery of methylalumoxane (MAO) as an activator in the late 1970's,4 a wide variety of high activity single-site transition metal catalyst systems have since been reported, including commercially relevant Group 4 metallocene systems,5 half-sandwich (constrained geometry) titanium catalysts,6 and non-metallocene systems based on a variety of nitrogen and oxygen donor ligands.

机译：在1970年代后期，在20世纪70年代后期，甲基铝氧烷（MAO）的偶然发现促进的聚烯烃，促进了多型催化剂技术，在过去的20年中获得了相当显着的进展。已经报道了分析金属催化剂体系，包括商业上相关的4组茂金属系统，5分半三明治（约束几何形状）钛催化剂，6和基于各种氮和氧供体配体的非茂金属系统。

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《Division of Polymeric Material: Science and Engineering American Chemical Society meeting》|2004年||共2页
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Atanas K. Tomov; Vernon C. Gibson; Damien Zaher;
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中图分类高分子化合物工业（高聚物工业）;
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1. Bis(benzimidazole) amine vanadium catalysts for olefin polymerisation and co-polymerisation: thermally robust, single-site catalysts activated by simple alkylaluminium reagents [J] . Tomov AK, Gibson VC, Zaher D, Chemical Communications . 2004,第17期

机译：用于烯烃聚合和共聚的双（苯并咪唑）胺钒催化剂：由简单的烷基铝试剂活化的耐热性，单中心催化剂
2. Vanadium(V) Complexes Containing Tetradentate Amine Trihydroxy Ligands as Catalysts for Copolymerization of Cyclic Olefins [J] . JI-QIAN WU, JING-SHAN MU, SEN-WANG ZHANG, Journal of Polymer Science, Part A. Polymer Chemistry . 2010,第5期

机译：含四齿胺三羟基配体的钒（V）络合物作为环状烯烃共聚合的催化剂
3. [ONNO]-type amine bis(phenolate)-based vanadium catalysts for ethylene homo- and copolymerization [J] . Lorber C Pure and Applied Chemistry . 2009,第7期

机译：[ONNO]型胺双酚盐型钒催化剂用于乙烯均聚和共聚
4. Bis(benzimidazole)amine Vanadium Catalysts for Olefin Polymerization and Copolymerization:Thermally Robust, Single-Site Catalysts Activated by Simple Alkylaluminum Reagents [C] . Atanas K. Tomov, Vernon C. Gibson, Damien Zaher Division of Polymeric Material: Science and Engineering American Chemical Society meeting . 2004

机译：BIS（苯并咪唑）胺钒催化剂用于烯烃聚合和共聚：通过简单的烷基铝试剂激活的热稳健，单现场催化剂
5. Alternating copolymerization of epoxides and carbon dioxide using single-site beta-diiminate zinc catalysts: Subtle modifications resulting in superior activities and evidence for a bimetallic epoxide enchainment. [D] . Moore, David Roger. 2003

机译：使用单中心β-二氨基锌催化剂交替进行环氧化合物和二氧化碳的共聚：细微的修饰导致优异的活性，并证明了双金属环氧化物的链结。
6. Observation of Different Catalytic Activity of Various 1-Olefins during Ethylene/1-Olefin Copolymerization with Homogeneous Metallocene Catalysts [O] . Mingkwan Wannaborworn, Piyasan Praserthdam, Bunjerd Jongsomjit 2011

机译：均相茂金属催化剂在乙烯/ 1-烯烃共聚过程中各种1-烯烃不同催化活性的观察
7. Progress in vanadium complex catalysts and their catalytic behavior toward copolymerization of ethylene with alpha;-olefins [O] . Shu Zhang, Xiaoyu Zhang, Yicong Wang, 2021

机译：钒络合物催化剂的进展及其对α-烯烃的乙烯共聚的催化性能
8. Summary of Health Effects Alleged by Property Occupants Following Potential Inhalation Exposure to Tertiary Amine Catalysts. These Catalysts, are N-methylmorpholine and bis(2dimethylaminoethyl) Ether. [R] . 2010

机译：可能吸入暴露于叔胺催化剂后财产受试者所称健康影响的摘要。这些催化剂是N-甲基吗啉和双（2-二甲基氨基乙基）醚。

Bis(benzimidazole)amine Vanadium Catalysts for Olefin Polymerization and Copolymerization:Thermally Robust, Single-Site Catalysts Activated by Simple Alkylaluminum Reagents

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