Peroxidase-Catalyzed Oxidative Coupling of Phenols in the Presence of Geosorbents

机译：过氧化物酶催化在地脂藻存在下酚的氧化偶联

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The effects of geosorbents on the enzymatically catalyzed coupling reactions of phenol are quantified and interpreted on the basis of a conceptual model advanced earlier. The work reveals that the reactivity of different sorbents with respect to cross-coupling with phenol radicals correlates with the chemical characteristics of the sorbents studied. Cross-coupling reactivities of the sorbents were found to decrease in the order lignin > Chelsea soil > Lachine shale > Polymethylstyrene; i.e., from humic-type organic matter (highly amorphous) to kerogen-like materials (relatively highly condensed). The information provided and insights gained from this study have important implications for the behavior and efficiency of enzymatic phenol coupling reactions that occur in natural environments, As such, they have utility in guiding remediation practices involving soil/sediment materials of different characteristics and properties.

机译：岩土吸收剂对苯酚酶催化偶联反应的影响是在先进的概念模型的基础上进行量化和解释。该工作表明，不同吸附剂与苯酚自由基交叉偶联的不同吸附剂的反应性与所研究的吸附剂的化学特征相关。发现吸附剂的交叉偶联反应性降低了木质素>切尔西土壤>植物植物>植物楸>聚甲基苯乙烯;即，从腐殖型有机物（高度无定形）到Kerogen样材料（相对高缩合）。本研究中获得的信息和见解对自然环境中发生的酶酚偶联反应的行为和效率产生了重要意义，因此它们具有涉及不同特征和性质的土壤/沉积物的引导修复实践。

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《American Chemical Society National Meeting》|2005年||共18页
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Qingguo Huang; Walter J. Weber Jr.;
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中图分类环境污染及其防治;
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1. Peroxidase-Catalyzed Coupling of Phenol in the Presence of Model Inorganic and Organic Solid Phases [J] . QINGGUO HUANG, WALTER J. WEBER Environmental Science & Technology . 2004,第19期

机译：在模型无机和有机固相存在下过氧化物酶催化的苯酚偶联
2. Peroxidase-catalyzed co-oxidation of 3,3 ',5,5 '-tetramethylbenzidine in the presence of substituted phenols and their polydisulfides [J] . Metelitza DI, Karasyova EI, Grintsevich EE, Journal of Inorganic Biochemistry: An Interdisciplinary Journal . 2004,第1期

机译：在取代酚及其多二硫化物存在下过氧化物酶催化的3,3'，5,5'-四甲基联苯胺的共氧化
3. Optimization of Peroxidase-Catalyzed Oxidative Coupling Process for Phenol Removal from Wastewater Using Response Surface Methodology [J] . SALEHE GHASEMPUR, SEYED-FAKHREDDIN TORABI, SEYED-OMID RANAEI - SIADAT, Environmental Science & Technology . 2007,第20期

机译：响应面法优化过氧化物酶催化氧化偶联工艺去除废水中的苯酚
4. Peroxidase-Catalyzed Oxidative Coupling of Phenols in the Presence of Geosorbents [C] . Qingguo Huang, Walter J. Weber Jr. American Chemical Society National Meeting . 2005

机译：过氧化物酶催化在地脂藻存在下酚的氧化偶联
5. A mechanistic study of peroxidase-catalyzed phenol coupling in water/soil/sediment systems. [D] . Huang, Qingguo. 2003

机译：在水/土壤/沉积物系统中过氧化物酶催化的苯酚偶联的机理研究。
6. Proposed Model for the Peroxidase-Catalyzed Oxidation of Indole-3-acetic Acid in the Presence of the Inhibitor Ferulic Acid [O] . D. A. Gelinas 1973

机译：在抑制剂阿魏酸存在下过氧化物酶催化的吲哚-3-乙酸氧化的拟议模型
7. Optimization of Peroxidase-Catalyzed Oxidative Coupling Process for Phenol Removal from Wastewater Using Response Surface Methodology [O] . -1

机译：用响应面法从废水中从废水中除去酚醛化催化氧化偶联方法的优化
8. Oxidative Coupling of Phenols on Activated Carbon: Impact on Adsorption Equilibrium [R] . Vidic, R. D., Suldan, M. T., Brenner, R. C. 1994

机译：酚类在活性炭上的氧化偶联反应对吸附平衡的影响

Peroxidase-Catalyzed Oxidative Coupling of Phenols in the Presence of Geosorbents

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