首页> 外文会议>China International Conference on High-Performance Ceramics >Preparation and Thermophysical Properties of (La_(0.4)Sm_(0.5)Yb_(0.1))_2(Zr_(0.7)Ce_(0.3))_2O_7 Ceramic for Thermal Barrier Coatings
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Preparation and Thermophysical Properties of (La_(0.4)Sm_(0.5)Yb_(0.1))_2(Zr_(0.7)Ce_(0.3))_2O_7 Ceramic for Thermal Barrier Coatings

机译:(LA_(0.4)SM_(0.5)YB_(0.1))_ 2(Zr_(0.7)CE_(0.3))_ 2O_7陶瓷的热阻挡涂层的制备和热物理性质

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摘要

A complex rare-earth zirconate (La_(0.4)Sm_(0.5)Yb_(0.1))_2(Zr_(0.7)Ce_(0.3))_2O_7 powder for thermal barrier coatings (TBCs) was synthesized by coprecipitation method. The phase composition, microstructure and the thermophysical properties were investigated. XRD results revealed that single phase (La_(0.4)Sm_(0.5)Yb_(0.1))_2(Zr_(0.7)Ce_(0.3))_2O_7 with pyrochlore structure was prepared and the SEM result showed that the microstructure of the product was dense and no other phases existed among the particles. With the temperature increasing, the thermal expansion coefficient (CTE) of the ceramic increased, while the thermal conductivity decreased. The results indicated that CTE of the ceramic was slightly higher than that of La_2Zr_2O_7 and the thermal conductivity of the ceramic was lower than that of La_2Zr_2O_7. These results imply that (La_(0.4)Sm_(0.5)Yb_(0.1))_2(Zr_(0.7)Ce_(0.3))_2O_7 can be explored as the candidate material for the ceramic layer in TBCs system.
机译:复杂的稀土锆(LA_(0.4)SM_(0.5)YB_(0.1))_ 2(Zr_(0.7)Ce_(0.3))_ 2O_7通过共沉淀法合成热阻挡涂层(TBC)。研究了相组合物,微观结构和热物理性质。 XRD结果显示,制备单相(LA_(0.4)SM_(0.5)YB_(0.1))_ 2(Zr_(0.7)CE_(0.3))_ 2O_7具有烧焦结构,SEM结果显示产品的微观结构密集颗粒中没有其他相位存在。随着温度的增加,陶瓷的热膨胀系数(CTE)增加,而导热率降低。结果表明陶瓷的CTE略高于La_2ZR_2O_7的CTE,陶瓷的导热率低于LA_2ZR_2O_7的导热率。这些结果意味着(LA_(0.4)SM_(0.5)YB_(0.1))_ 2(Zr_(0.7)CE_(0.3))_ 2O_7可以探索为TBCS系统中陶瓷层的候选材料。

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