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首页> 外文会议>Materials Research Society Symposium on Organic Electronics >Electrochemical Depositon of End-Capped Triarylamine and CBP Dendrimers: Alternate Technique for the Fabrication of Organic Light-Emitting Devices
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Electrochemical Depositon of End-Capped Triarylamine and CBP Dendrimers: Alternate Technique for the Fabrication of Organic Light-Emitting Devices

机译：端盖三际的电化学沉积和CBP树枝状大分子：用于制造有机发光器件的替代技术

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End-capped triarylamine and carbazole dendrimers were prepared through the divergent synthesis based on the reaction of diethenyl propagating carbosilane dendrimers with suitable functional groups such as the naphthylphenylaminophenyl (NPB) or carbazolylphenyl (CBP) unit. The electrochemical deposition behavior in higher generation dendrimer was observed in cyclovoltammetric experiments, leading to the good film formation on ITO. The deposited films remained intact in the depositing solvent and the film thickness was adjusted by varying the number of CV cycles. To obtain the reason of this behavior, the electrochemical property of compounds based on silicon (Me{sub}(4-n)Si(CBP){sub}n) was systematically studied. Moreover, multi-layer films could be fabricated without causing any damage to the previous layer. To this ends, the fabrication of OLEDs using this electrochemical deposition process was also investigated.
机译：通过基于二乙基硅烷树枝状蛋白（如萘基苯基氨基苯基（NPB）或咔唑基苯基（CBP）单位）的二甲烯基的反应，通过发散合成来制备端盖式三芳基胺和咔唑树枝状蛋白。在环伏末验实验中观察到较高发电树树枝状器中的电化学沉积行为，导致ITO上的良好膜形成。沉积的薄膜在沉积溶剂中保持完整，通过改变CV循环的数量来调节膜厚度。为了获得这种行为的原因，系统地研究了基于硅（ME {Sub}（4-N）Si（CBP）Si（CBP）} N）的化合物的电化学性质。此外，可以制造多层膜而不会导致前一层损坏。为此，还研究了使用这种电化学沉积过程的OLED的制造。

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