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Hexavalent Chromate Removal from Wastewater Using Micellar EnhancedUltrafiltration and Activated Carbon Fibre Processes; Validation of Experiment with Mathematical Equations

机译:六价铬酸盐使用胶束增强型玻璃料和活性炭纤维工艺从废水中除去;数学方程验证实验

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Industrial wastewater containing toxic compounds are of great concern regarding its disposal to the environment. Micellar enhanced ultrafiltration (MEUF) has its important role in removing low molecular size inorganic metals and organics. In this study, chromate and cetylperidinium chloride (CPC) removal from wastewater was evaluated using MEUF and activated carbon fibre (ACF) hybrid processes. For the efficient chromate removal, molar concentration of CPC should be five times that of chromate and it should be at least one critical micelle concentration (CMC). Chromate removal from MEUF was over 97% and CPC was ranged from 50% to 70% with larger pore size membrane of molecular weight cut-off (MWCO) of 100 KD. By the addition of ACF unit, chromate and CPC removal increased to 99.8%. MEUF was found to be effective in chromate removal while ACF in CPC adsorption to produce chromate and CPC free effluent. Based on the regression analysis, validity of the experimental result was well defined by power and exponential functional relationship of effluent chromate concentration with the other independent variables such as pH, initial chromate concentration, molar ratio and initial CPC concentrations.
机译:含有有毒化合物的工业废水有关其对环境的可能性很大。胶束增强超滤(MEUF)在去除低分子尺寸无机金属和有机物方面具有重要作用。在该研究中,使用MEUF和活性炭纤维(ACF)杂化方法评价从废水中除去废水中的铬酸盐和氯化酰氯丙啶(CPC)。为了去除有效的铬酸盐,CPC的摩尔浓度应为铬酸盐的五倍,并且它应该是至少一种临界胶束浓度(CMC)。来自MEUF的铬酸盐除草超过97%,CPC的范围为50%至70%,分子量截止的孔尺寸膜(MWCO)为100kd。通过添加ACF单元,铬酸盐和CPC去除增加到99.8%。发现MEUF在CPC吸附中的铬酸盐除去时有效,以产生铬酸盐和CPC自由流出物。基于回归分析,实验结果的有效性通过与其他独立变量的流出铬酸盐浓度的功率和指数函数关系良好地定义,例如pH,初始铬酸盐浓度,摩尔比和初始CPC浓度。

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