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Evaluation of Heavy Metals in Solid Waste Disposal Sites in Campinas City, Brazil Using Synchrotron Radiation Total Reflection X-Ray Fluorescence

机译:在坎皮纳斯城市固体废物处理场所的重金属评估使用同步辐射全反射X射线荧光

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The problem of solid waste in most countries is on the rise as a result of rapid population growth, urbanization, industrial development and changes in consumption habits. Amongst the various forms of waste disposals, landfills are today the most viable for the Brazilian reality, both technically and economically. Proper landfill construction practices allow minimizing the effects of the two main sources of pollution from solid waste: landfill gas and slurry. However, minimizing is not synonymous with eliminating; consequently, the landfill alone cannot resolve all the problems with solid waste disposal. The main goal of this work is to evaluate the content of trace elements in samples of groundwater, surface water and slurry arising from local solid waste disposals in the city of Campinas, SP, Brazil. Samples were collected at the Delta, Santa Barbara and Pirelli landfills. At the Delta and Santa Barbara sites, values above the maximum permitted level established by CETESB for Cr, Mn, Fe, Ni and Pb were observed in samples of groundwater, while at the Pirelli site, elements with concentrations above the permitted levels were Mn, Fe, Ba and Pb. At Delta, values above levels permitted by the CONAMA 357 legislation were still observed in surface water samples for Cr, Mn, Fe and Cu, whereas in slurry samples, values above the permitted levels were observed for Cr, Mn, Fe, Ni, Cu, Zn and Pb. Slurry samples were prepared in accordance with two extraction methodologies, EPA 3050B and EPA 200.8. Concentrations of Cr, Ni, Cu and Pb were higher than the limit established by CONAMA 357 for most samples collected at different periods (dry and rainy) and also for the two extraction methodologies employed.
机译:由于人口增长,城市化,工业发展,消费习惯的变化,大多数国家在大多数国家的固体废物问题正在上升。在各种形式的废物处理中,垃圾填埋场今天是巴西现实最可行的,技术上和经济。适当的垃圾填埋场建设措施允许最大限度地减少两种主要污染源的影响:垃圾填埋气体和浆料。然而,最小化不是消除的同义词;因此,垃圾填埋场无法解决固体废物处理的所有问题。这项工作的主要目的是评估地下水,地表水和浆料样品中的微量元素的含量,这些阵列在巴西坎皮纳斯市坎帕纳斯市局部固体废物处理中产生的。在Delta,Santa Barbara和Pirelli垃圾填埋场收集样品。在Delta和Santa Barbara网站上,在地下水的样品中观察到由CETESB建立的最大允许级别的值,而在地下水的样品中,在Pirelli位点,允许高于允许水平的元素为Mn, Fe,Ba和Pb。在三角洲,在Cr,Mn,Fe和Cu的地表水样中仍观察到互联网357立法的高度的值,而在浆料样品中,对于Cr,Mn,Fe,Ni,Cu,Cu,Cu,Cu,Cu ,zn和pb。根据两种提取方法,EPA 3050B和EPA 200.8制备浆液样品。 CR,Ni,Cu和Pb的浓度高于Conama 357,用于在不同时期收集的大多数样品(干燥和雨水)以及所用的两种提取方法。

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