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The Crystal Morphology and Molecular Orientation Influence of Electrospun Polyacrylonitrile Copolymer Nanofibers with Different Diameters

机译:电纺聚丙烯腈共聚物纳米纤维具有不同直径的晶体形态和分子取向影响

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Pan-based carbon fiber has enormous commercial applications due to its high modulus and high strength. But in recent decades there has no great progress in tensile strength and modulus of pan-based carbon fiber [1]. The primary reason is the heterogeneity of internal defects such as fiber surface groove, wire surface defects, and crystallinities [2,3]. In order to obtain good performance of carbon fiber, the fine denier, high purification, micro crystallization and homogenizing polyacrylonitrile base of the original silk is the primary premise. Electrostatic spinning broke limitations of the conventional dry spinning as well as the dry-jet wet-spinning, which can be used to prepare the nanometer level precursor, thus make the pan-based carbon fiber huge properties of ascension may provide the witnessed [4,5]. However, in electrostatic spinning, how to pure research diameter of fiber for fiber morphology and the influence of the structure and the other factors into has been bothering you. In this paper, to solve the stability of continuous flow water bath collection system, and on the basis of electrostatic spinning process through simple changes in the flow velocity of the spinning solution, get the different diameter of electrostatic spinning polyacrylonitrile fiber the nano [6]. The diameter changes of electrostatic spinning polyacrylonitrile fiber and morphology of the nano gathered state the influence of the structure were also investigated.
机译:由于其高模量和高强度,泛碳纤维具有巨大的商业应用。但近几十年来,泛料碳纤维的拉伸强度和模量没有巨大进展[1]。主要原因是内部缺陷的异质性,例如纤维表面槽,线表面缺陷和晶体化[2,3]。为了获得碳纤维的良好性能,原始丝绸的细旦尼尔,高纯化,微结晶和均化聚丙烯腈基础是初级前提。静电纺丝突破常规干纺的局限性以及可用于制备纳米级前体的干式湿旋转,从而使泛碳纤维的巨大性质升高可以提供所见证的[4, 5]。但是,在静电纺丝中,如何纯化纤维的纤维研究直径和结构的影响和其他因素一直困扰着你。在本文中,为了解决连续流水浴收集系统的稳定性,并在静电纺丝过程的基础上通过简单地改变纺丝溶液,得到不同直径的静电纺丝聚丙烯腈纤维纳米[6] 。静电纺丝聚丙烯腈纤维的直径变化和纳米聚集状态的形态也研究了结构的影响。

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