SYNTHESIS OF FUNCTIONALIZED ALIPHATIC POLYESTERS BY THE 'CLICK' COPPER-CATALYZED ALKYNE-AZIDE CYCLOADDITION

机译：通过“点击”铜催化的炔芳酮 - 叠氮化物环加成合成官能化脂族聚酯

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The functionalization of aliphatic polyesters by the copper-mediated azide-alkyne Huisgen's cycloaddition is very efficient under mild conditions, which prevents degradation from occurring. The implementation of this reaction requires the synthesis of aliphatic polyesters bearing pendant alkynes and azides, which can be carried out either by polycondensation or by ring-opening poly-merization.

机译：通过铜介导的叠氮化物 - 炔烃Huisgen的环加成在温和条件下非常有效的脂族聚酯的官能化非常有效，这可以防止发生降解。该反应的实施需要合成含有侧链炔烃和叠氮化物的脂族聚酯，其可以通过缩聚或通过开环多合并进行。

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来源
《NATO Advanced Study Institute on New Smart Materials via Metal Mediated Macromolecular Engineering: from Complex to Nano Structures》|2009年||共15页
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作者
PHILIPPE LECOMTE; RAPHAEL RIVA; CHRISTINE JEROME;
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中图分类 TB381-532;
关键词
Ring-opening polymerization; Aliphatic polyester; Copper-mediated azide-alkyne cycloaddition; Click chemistry;

机译：开环聚合;脂肪族聚酯;铜介导的叠氮化物 - 炔环加油;点击化学;

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1. First example of "click" copper(I) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: application to the functionalization of aliphatic polyesters [J] . Bruno Grignard, Stephanie Schmeits, Raphael Riva Green chemistry . 2009,第10期

机译：超临界二氧化碳中“点击”铜（I）催化的叠氮化物-炔烃环加成反应的第一个例子：在脂族聚酯官能化中的应用
2. Rapid Synthesis of Functionalized High-Generation Polyester Dendrimers via Strain-Promoted Alkyne-Azide Cycloaddition [J] . McNelles Stuart A., Adronov Alex Macromolecules . 2017,第20期

机译：通过应变促进的炔芳烃环加成快速合成官能化的高代涤纶树枝状大分子
3. Tao-Phos-controlled desymmetrization of succinimide-based bisalkynes via asymmetric copper-catalyzed Huisgen alkyne-azide click cycloaddition: substrate scope and mechanism [J] . Chen Mu-Yi, Song Tao, Zheng Zhan-Jiang, RSC Advances . 2016,第63期

机译：通过非对称铜催化的琥珀酰亚胺的双链条的TAO-PHOS控制的取差异化Huisgen alkyne-叠氮化物点击环加入：基板范围和机制
4. SYNTHESIS OF FUNCTIONALIZED ALIPHATIC POLYESTERS BY THE "CLICK" COPPER-CATALYZED ALKYNE-AZIDE CYCLOADDITION [C] . PHILIPPE LECOMTE, RAPHAEL RIVA, CHRISTINE JEROME NATO Advanced Study Institute on New Smart Materials via Metal Mediated Macromolecular Engineering: from Complex to Nano Structures . 2009

机译：通过“点击”铜催化的炔芳酮 - 叠氮化物环加成合成官能化脂族聚酯
5. Synthesis and characterization of cyclic polystyrene using copper-catalyzed alkyne-azide cycloaddition coupling - evaluation of physical properties and optimization of cyclization conditions. [D] . Elupula, Ravinder. 2016

机译：使用铜催化的炔-叠氮化物环加成偶联反应合成和表征环状聚苯乙烯-物理性质评估和环化条件优化。
6. Biotin-Conjugated Cellulose Nanofibers Prepared via Copper-Catalyzed Alkyne-Azide Cycloaddition (CuAAC) Click Chemistry [O] . Katarina Goodge, Margaret Frey 2020

机译：通过铜催化的炔-叠氮化物环加成（CuAAC）点击化学制备的生物素共轭纤维素纳米纤维
7. New developments in the functionalization of aliphatic polyesters by "click" copper-catalyzed azide-alkyne cycloaddition [O] . Lecomte, Philippe, Riva, Raphaël, Schmeits, Stephanie, 2009

机译：通过“点击”铜催化的叠氮化物-炔烃环加成反应在脂肪族聚酯官能化方面的新进展

SYNTHESIS OF FUNCTIONALIZED ALIPHATIC POLYESTERS BY THE 'CLICK' COPPER-CATALYZED ALKYNE-AZIDE CYCLOADDITION

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