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The Effect of Posterior Disposal Process on Gel Viscosity of Montmorillonite/octadecyl Trimethy Ammonium Chloride Complexes

机译:后处理过程对蒙脱石/十八甲基氯化铵复合物凝胶粘度的影响

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Thixotropic gel can be formed in the organic solvents is one of the most important application characteristics of montmorillonite/octadecyl trimethy ammonium chloride complexes. The key factor influencing the formation of gel is the preparation technology, and the posterior disposal process is also an important affecting factor which should be paid more attention to. In the paper, the effects of washing, drying temperature, grind size, activators and the polarity of solvents on the gel viscosity of montmorillonite/octadecyl trimethy ammonium chloride complexes were systematically studied. The research shows that fully washing can elute the octadecyl trimethy ammonium chloride ions or molecula adsorbed on the layer and the edge of montmorillonite crystal, and improve viscosity of gel formed by the complexes. Controlling the drying temperature at the range of 90- 100°C and ensuring the complexes with a little interlayer water are favorable for the gel formation of the complexes. When the granularity of the complexes is less than 0.074mm, particles in solvents can fully produce solvation action, solvent swells and strips, and then form the thixotropic organic gel. Using the 95% ethanol as the activator, when its dosage is 5 wt%, its activation effect is better. The stronger the polarity of the dispersing solvent is, the more favorable the formation of the organic gel with higher viscosity is.
机译:可以在有机溶剂中形成触变性凝胶是蒙脱石/十八烷基三甲基氯化铵配合物最重要的应用特征之一。影响凝胶形成的关键因素是制备技术,后部处理过程也是应该更加关注的重要影响因素。本文研究了洗涤,干燥温度,研磨尺寸,活化剂和溶剂对蒙脱石/十四烷基三甲基氯化铵复合物的凝胶粘度的影响。该研究表明,完全洗涤可以在层和蒙脱石晶体上吸附的十四烷基三甲基氯离子离子或分子,并提高由配合物形成的凝胶的粘度。将干燥温度控制在90-100℃的范围内,并确保具有小层间水的络合物是有利于粘合剂的凝胶形成。当络合物的粒度小于0.074mm时,溶剂中的颗粒可以完全产生溶剂化作用,溶剂溶胀和条带,然后形成触变性有机凝胶。使用95%乙醇作为活化剂,当其剂量为5wt%时,其活化效果更好。分散溶剂的极性越强,具有较高粘度的有机凝胶的形成越有利。

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