Analysis of the Solubility of TNT and RDX in TNT/RDX/SC-CO_2

机译：TNT和RDX在TNT / RDX / SC-CO_2中的溶解度分析

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The solubility of TNT and RDX was measured in supercritical carbon dioxide fluid at 303.0, 308.0, 323.0, 338.0 K, and over the pressure range from 10.0 MPa to 50.0 MPa. This study examined the influences of extraction temperature, extraction pressure and support effect (SE) between molecules of TNT and RDX on their solubility in the TNT/RDX/SC-CO_2 system. The results show that solubility of TNT and RDX in TNT/RDX/SC-CO_2 ternary system is much higher than that in binary system. The values of SE of RDX and TNT increase first and decrease then with the pressure changing. The pressure turning point occurred over the pressure range from 25 MPa to 28 MPa for TNT and from 13 MPa to 20 MPa for RDX.

机译：在303.0,308.0,323.0,338.0k的超临界二氧化碳流体中测量TNT和RDX的溶解度，并在10.0MPa至50.0MPa的压力范围内测量。该研究检测了TNT和RDX分子在TNT / RDX / SC-CO_2系统中溶解度的提取温度，提取压力和支持效应（SE）的影响。结果表明，TNT / RDX / SC-CO_2三元系统中TNT和RDX的溶解度远高于二元系统中的TNT和RDX。 RDX和TNT的SE值首先增加和减少随压变化。压力转弯点在压力范围内发生25MPa至28MPa的TNT和RDX的13 MPa至20MPa。

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《International Conference on Machinery, Materials Science and Engineering Applications》|2014年||共4页
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作者
Wensu Ji; Yukui Ding; Yuqiu Xu;
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中图分类 TB3-53;
关键词
TNT; RDX; Explosive; Supercritical Fluid Extraction; Solubility; Equilibrium;

机译：tnt;rdx;爆炸;超临界流体提取;溶解性;平衡;

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专利

1. RDX solubility in TNT at high temperatures [J] . Hobbs Michael L., Kaneshige Michael J., Todd Steven N., Journal of thermal analysis and calorimetry . 2020,第2期

机译：在高温下TNT的RDX溶解度
2. Effects of pH and Temperature on the Aqueous Solubility and Dissolution Rate of 2,4,6-Trinitrotoluene (TNT), Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) [J] . Jason C.Lynch, Karen F.Myers, James M.Brannon Journal of Chemical and Engineering Data: the ACS Journal for Data . 2001,第6期

机译：pH和温度对2,4,6-三硝基甲苯（TNT），六氢-1,3,5-三硝基-1,3,5-三嗪（RDX）和Octahydro-1的水溶性和溶解速率的影响， 3,5,7-四硝基-1,3,5,7-四唑嗪（HMX）
3. Models for predicting solubilities of 2,4,6-trinitrotoluene (TNT) and 1,3,5-trinitro-1,3,5-s-triazine (RDX) in supercritical CO2: isothermal-isobaric Monte Carlo simulations [J] . Agrawal PA., Sorescu DC., Thompson DL., Fluid Phase Equilibria . 2001,第0期

机译：预测2,4,6-三硝基甲苯（TNT）和1,3,5-三硝基-1,3,5-s-三嗪（RDX）在超临界CO2中的溶解度的模型：等温-等压蒙特卡罗模拟
4. Analysis of the Solubility of TNT and RDX in TNT/RDX/SC-CO_2 [C] . Wensu Ji, Yukui Ding, Yuqiu Xu International Conference on Machinery, Materials Science and Engineering Applications . 2014

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5. Biological treatment of 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), and the hydrolysates of RDX and HMX. [D] . Reinhart, George Albetz, III. 2001

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6. Transcriptomic analysis of RDX and TNT interactive sublethal effects in the earthworm Eisenia fetida [O] . Ping Gong, Xin Guan, Laura S Inouye, 2008

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7. Evaluation of the metabolic fate of munitions material (TNT & RDX) in plant systems and initial assessment of material interaction with plant genetic material. Validation of the metabolic fate of munitions materials (TNT, RDX) in mature crops [O] . Fellows, R.J., Harvey, S.D., Cataldo, D.A. 1995

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8. Evaluation of the metabolic fate of munitions material (TNT & RDX) in plant systems and initial assessment of material interaction with plant genetic material. Validation of the metabolic fate of munitions materials (TNT, RDX) in mature crops [R] . Fellows, R. J., Harvey, S. D., Cataldo, D. A. 1995

机译：评估植物系统中弹药材料（TNT和RDX）的代谢命运以及材料与植物遗传物质相互作用的初步评估。验证成熟作物中弹药材料（TNT，RDX）的代谢命运

Analysis of the Solubility of TNT and RDX in TNT/RDX/SC-CO_2

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