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Research on The Preparation of AgCl/C_(12)mimCl-PMMA Inorganic-Organic Hybrid Membranes via Ionic Liquid-Microemulsion Polymerization

机译:通过离子液体微乳液聚合制备ACCl / C_(12)MIMCL-PMMA无机 - 有机杂交膜的制备研究

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AgCl/C_(12)mimCl-PMMA inorganic-organic hybrid membranes were prepared via ionic liquid-microemulsion polymerization. And in this microemulsion system, ionic liquid (1-dodecyl-3-methyl imidazoium chloride) served as the surfactant, methyl methacrylate served as the oil. The morphology, particle size and size distribution were characterized by UV-vis and TEM. The results revealed that the AgCl nanoparticles in microemulsion were spherical or sphere-like, the average diameter was below 8nm and its attribution was relatively narrow. The SEM showed AgCl nanoparticles were evenly dispersed in hybrid membranes. The swelling-sorption behaviors of the cyclohexane/cyclohexene in hybrid membranes were studied. The results indicated that the hybrid membranes' maximum swelling-sorption amount of cyclohexene was up to 447, which was larger than that of cyclohexane(96).
机译:通过离子液 - 微乳液聚合制备AgCl / C_(12)MIMCL-PMMA无机 - 有机杂化膜。在该微乳液系统中,离子液体(1-十二烷基-3-甲基咪唑氯化氢)用作表面活性剂,甲基丙烯酸甲酯用作油。通过UV-Vis和TEM表征了形态,粒度和尺寸分布。结果表明,微乳液中的AgCl纳米颗粒是球形或球形的,平均直径低于8nm,其归因相对较窄。 SEM显示的ACCL纳米颗粒均匀地分散在杂交膜中。研究了杂交膜中环己烷/环己烯的肿胀吸附行为。结果表明,杂化膜的最大溶胀吸附量高达447,其大于环己烷(96)。

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