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Effect of the sols' zinc ions' concentration on structural and optical properties of (Cu, Al) co-doped ZnO thin film by sol - gel method

机译:溶胶锌离子浓度对溶胶 - 凝胶法(Cu,Al)共掺杂ZnO薄膜结构和光学性质的影响

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(Cu-Al) co-doped ZnO thin films were deposited on glass substrate by the sol-gel method using the spin coating technique. The crystalline phase structure of the films were analyzed by X-ray diffraction. The photoluminescence spectra of samples were measured by fluorescence spectrophotometer. The results show that these films have a compact hexagonal wurtzitetype structure five peaks have been observed from the PL spectra of the all samples, 367nm (3.38eV), 398nm (3.12eV), 450nm(2.759eV), 483nm(2.57eV) and 468nm(2.653eV). It is concluded that the violet peak may correspond to the excit on emission, the blue emission corresponds to the electron transition from the bottom of the conduction band to the accept or level of zinc vacancy.
机译:(Cu-Al)通过使用旋涂技术通过溶胶 - 凝胶法在玻璃基板上沉积有共掺杂的ZnO薄膜。通过X射线衍射分析薄膜的结晶相结构。通过荧光分光光度计测量样品的光致发光光谱。结果表明,这些薄膜具有紧凑型六边形Wurtzitype结构,从所有样品的PL光谱观察到五个峰,367nm(3.38ev),398nm(3.12ev),450nm(2.759ev),483nm(2.57ev)和468nm(2.653ev)。结论是,紫色峰值可以对应于发射时的激励,蓝色发射对应于从导电带的底部到接受或锌空位的电子转变。

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