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Oxidative Esterification of Methacrolein to Methyl Methacrylate over La Doped Catalyst

机译:La掺杂催化剂上甲基丙烯酸甲酯甲基丙烯醛的氧化酯化

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In this present work, rare earth elements La was added to catalysts for the oxidative esterification of methacrolein (MAL) to methyl methacrylate(MMA). Catalysts were characterized by means of BET techniques. Effects of La proportion, material liquid pH and catalyst amount on catalytic performance were investigated. The results indicated that the addation of La in appropriate proportion could improve the catalyst's activity. 1.0% was found to be the optimum La additional amount. Under the condition of reation temperature 323K, w%(catalyst) 3.6%, proportion of La in the catalyst 1%, pH of material liquid 10.0 the MMA yield could reached up to 89.8%.
机译:在本工作中,将稀土元素LA加入到甲基丙烯醛(MA)甲基丙烯酸甲酯(MMA)的氧化酯化的催化剂中。通过BET技术表征催化剂。研究了La比例,材料液pH和催化剂量对催化性能的影响。结果表明,以适当比例的含量可以改善催化剂的活性。 1.0%被发现是最佳的La额外金额。在加油温度的条件下,W%(催化剂)3.6%,催化剂中的La比例1%,材料液体10.0的pH值达到89.8%。

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