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Hexabenzocoronenes Bearing Odd Carbon Alkyl Chains as Columnar Discotic Liquid Crystal

机译:含奇碳烷基链作为柱状光盘液晶

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Two HBC derivatives (HBC-C_(13) and HBC-C_(15)), both containing 6 odd-carbon alkyl chains surrounding the rigid plane core, were investigated as discotic liquid crystal. The difference between their thermal behaviors has been investigated by using differential scanning calorimetry (DSC). Their mesomorphic phase behavior was observed by polarizing optical microscopy (POM). A remarkable odd-even effect in the phase transition temperatures was observed for all HBC derivatives (HBC-C_(123), HBC-C_(13), HBC-C_(14), HBC-C_(15) and HBC-C_(16)).
机译:研究了两种HBC衍生物(HBC-C_(13)和HBC-C_(15)),均含有围绕刚性平面芯的6个奇碳烷基链,作为盘状液晶。通过使用差示扫描量热法(DSC)研究了其热行为之间的差异。通过偏振光光学显微镜(POM)观察它们的中间形相行为。对于所有HBc衍生物(HBC-C_(123),HBC-C_(13),HBC-C_(14),HBC-C_(15)和HBC-C_(HBC-C_(15)和HBC-C_()观察到相位转变温度的奇数甚至效果16))。

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