Systematics in the formation of lanthanide halide compounds

机译：在形成镧卤化物化合物的系统中

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The phase diagrams of trivalent lanthanide-alkali metal halide systems range from simple eutectic systems to systems with one (several) congruently or incongruently melting compounds. Using both literature information and our extensive experimental results, the LnX3-MX binary mixtures phase diagrams were screened in terms of the IPM+/IPLn3+ ratio (IPi= zi/ri ; zi: ionic charge; ri: ionic radius; Ln: lanthanide, X: halide and M: alkali metal). A similar approach was conducted on the divalent LnX2-MX lanthanide-alkali halides phase diagrams ranging from simple eutectic to one or more congruently melting compounds. Lanthanides being widely used as simulants of actinides, this classification can constitute a useful predictive tool for those still unexplored systems.

机译：三价镧系碱金属卤化物系统的相图因此从简单的共晶体系到具有一个（几种）的熔融化合物的系统中的简单共晶体系。利用文献信息和我们的广泛实验结果，就IPM + / IPLN3 +比（IPI = ZI / RI; ZI：离子电荷; RI：离子半径; LN：镧系元素，X.）筛选LNX3-MX二元混合物相分图：卤化物和M：碱金属）。在二价LNX2-MX镧系里卤化物相卤化物相图中进行了一种类似的方法，从简单的共晶到一种或多种一致熔化的化合物。 Lanthanides被广泛用作贴滑石的模拟剂，该分类可以构成那些仍然未开发的系统的有用预测工具。

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《International conferece on molten slags, fluxes and salts》|2012年||共13页
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Marcelle Gaune-Escard; Leszek Rycerz; Ewa Ingier-Stocka; Slobodan Gadzuric;
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中图分类原材料;
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Lanthanide; alkali metal; halide; mixture; phase diagram; topology; ionic potential; prediction;

机译：镧;碱金属;卤化物;混合;相位图;拓扑;离子潜力;预测;

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1. Compound formation in lanthanide-alkali metal halide systems .... [J] . Marcelle Gaune-Escard, Leszek Rycerz, Ewa Ingier-Stocka Transactions of the Institutions of Mining and Metallurgy, Section C. Mineral Processing and Extractive Metallurgy . 2014,第1期

机译：镧系元素-碱金属卤化物体系中的化合物形成....
2. Controllable Formation of Heterotrimetallic Coordination Compounds: Systematically Incorporating Lanthanide and Alkali Metal Ions into the Manganese 12-Metallacrown?4 Framework [J] . Michael R. Azar, Thaddeus T. Boron, Jacob C. Lutter, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2014,第3期

机译：三金属配位化合物的可控形成：将镧系元素和碱金属离子系统性地掺入锰12-金属lac 4骨架中
3. Systematics of lanthanide and actinide compound formation: remarks on the americium alloying behaviour [J] . R. Ferro, G. Cacciamani, A. Saccone Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2001,第2期

机译：镧系元素和act系元素形成的体系：关于re合金行为的评论
4. Systematics in the formation of lanthanide halide compounds [C] . Marcelle Gaune-Escard, Leszek Rycerz, Ewa Ingier-Stocka, Ninth international conferece on molten slags, fluxes and salts . 2012

机译：镧系元素卤化物形成过程中的系统学
5. A study of the structural, magnetic, optical, and electronic properties of several new copper(II) halide and copper(II,I) halide compounds in the solid state. [D] . Scott, Brian Lindley. 1990

机译：对几种新型固态卤化铜（II）和卤化铜（II，I）化合物的结构，磁性，光学和电子性质的研究。
6. Growth and Characterization of Polycrystalline Lanthanide Halide Scintillators [O] . V.V. Nagarkar, S.R. Miller, V. Gelfandbein, -1

机译：多晶镧卤化物闪烁体的生长和表征
7. Formation and Encapsulation of Lead Halide Perovskites in Lanthanide MetalOrganic Frameworks for Tunable Emission [O] . -1

机译：镧系元素金属有机骨架铅卤化铅钙矿的形成和封装，可调发射
8. Vapor Phase Spectroscopy of Complex Lanthanide Halide--Aluminum Halide Molecular Species [R] . Carnall, W. T., Hessler, J. P., Williams, C. W., 1977

机译：复合镧系卤化物 - 卤化铝分子种的气相光谱

Systematics in the formation of lanthanide halide compounds

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