首页> 外文会议>Ninth international conferece on molten slags, fluxes and salts >Systematics in the formation of lanthanide halide compounds
【24h】

Systematics in the formation of lanthanide halide compounds

机译:镧系元素卤化物形成过程中的系统学

获取原文
获取原文并翻译 | 示例

摘要

The phase diagrams of trivalent lanthanide-alkali metal halide systems range from simple eutectic systems to systems with one (several) congruently or incongruently melting compounds. Using both literature information and our extensive experimental results, the LnX3-MX binary mixtures phase diagrams were screened in terms of the IPM+/IPLn3+ ratio (IPi= zi/ri ; zi: ionic charge; ri: ionic radius; Ln: lanthanide, X: halide and M: alkali metal). A similar approach was conducted on the divalent LnX2-MX lanthanide-alkali halides phase diagrams ranging from simple eutectic to one or more congruently melting compounds. Lanthanides being widely used as simulants of actinides, this classification can constitute a useful predictive tool for those still unexplored systems.
机译:三价镧系元素-碱金属卤化物体系的相图范围从简单的共晶体系到具有一种(数个)完全或不完全熔融的化合物的体系。利用文献资料和广泛的实验结果,根据IPM + / IPLn3 +比率(IPi = zi / ri; zi:离子电荷; ri:离子半径; Ln:镧系元素,X)筛选了LnX3-MX二元混合物相图。 :卤化物,M:碱金属)。对二价LnX2-MX镧系元素-碱金属卤化物相图进行了类似的研究,范围从简单的共晶到一个或多个完全熔化的化合物。镧系元素被广泛用作act系元素的模拟物,这种分类可以为那些尚未开发的系统提供有用的预测工具。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号