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Low Temperature Carbon Monoxide Sensor Based on Co(salen) Doped PEDOT: PSS

机译:基于CO(Salen)掺杂PEDOT的低温一氧化碳传感器:PSS

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Poly (3, 4-ethylenedioxy thiophene) - poly (styrenesulfonate) (PEDOT:PSS) was used as a sensing matrix to fabricate a chemical carbon monoxide (CO) sensor. A Co(salen) complex was doped into the polymer matrix in various ratios to improve its response and selectivity to CO gas. The probe was examined to some common gases in the atmosphere, such as O_2, N_2, and CO_2 to evaluate its responsibility. This showed satisfactory response to CO which was different it from other gases. The response of the composite to CO was reversible (RSD < 5%) change in resistance upon removal of CO gas from the test chamber. The doped polymer was characterized by Fourier Transform Infrared Spectroscopy (FT-IR) and UV-visuble spectroscopy (UV). Also, The effects of adding Co(salen) in the probe film on the response of the sensor were investigated by X-ray Photoelectron Spectroscopy (XPS). The dependence of the sensor response to the Co(salen) concentration was studied in the range of 0-1.5 wt.%. The highest response was obtained at 1.0 wt.% Co(salen) in the composite (25% ± 0.05).
机译:聚(3,4-亚乙二醇噻吩) - 聚(苯乙烯磺酸盐)(PEDOT:PSS)用作传感基质以制造化学一氧化碳(CO)传感器。将Co(沙仑)配合物掺杂到以各种比例的聚合物基质以改进其响应和选择性CO气体。将探针检测到大气中的一些普通气体,例如O_2,N_2和CO_2,以评估其责任。这表明对来自其他气体不同的CO的令人满意的反应。复合材料与CO的响应是可逆的(RSD <5%)在从测试室移除CO气体时的抗性变化。掺杂的聚合物的特征在于傅里叶变换红外光谱(FT-IR)和UV-求求光谱(UV)。此外,通过X射线光电子能谱(XPS)研究了在探针膜上添加CO(Salen)对传感器响应的影响。在0-1.5重量%的范围内,研究了传感器对CO(Salen)浓度的依赖性。%。在1.0重量%的重量下获得最高反应。%CO(Salen)在复合材料中(25%±0.05)。

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