Europium(III) ion detection in water by a new luminescent optical fibre sensor

机译：铕（III）通过新的发光光纤传感器在水中检测

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A new europium(III) luminescent optical fibre sensor based on a tridentate bis(phosphinic amide)-phosphine oxide PhPO(C_6H_4POPhN(CH(CH_3)_2)_2)_2 is described. The ligand was successfully immobilized on PVC membrane on optical fibre by dip coating technique. The reaction between europium(III) ion and ligand produced a strong luminescent complex of stoichiometry [1:2], which possessed a maximum emission peak at 612 nm. The sensor luminescence response showed an exponential behavior versus logarithmic concentration of europium(III) ions (10~(-8) - 10~(-3) M) in aqueous solution with a correlation factor of R~2 = 0.9918, and an acceptable response time (t_(90)-t_(10)) of 92 seconds. This optode is the first luminescent optical fibre sensor for detecting europium(III) ions in water.

机译：描述了一种基于三齿双（膦酰胺酰胺） - 氧化膦PHPO（C_6H_4POPHN（CH（CH_3）_2 _2）_2的新型铕（III）发光光纤传感器。通过浸涂技术在光纤上成功地固定在PVC膜上的固定体。铕（III）离子和配体之间的反应产生了化学计量[1：2]的强发光络合物，其在612nm处具有最大排放峰。传感器发光响应显示了水溶液中铕（III）离子（III）离子（III）离子（III）离子（10〜（-8） - 10〜（-3）m）的指数行为，具有R〜2 = 0.9918的相关因子，以及可接受的响应时间（t_（90）-t_（10））为92秒。该光电极是第一发光光纤传感器，用于检测水中的铕（III）离子。

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《International Meeting on Chemical Sensors》|2012年||共3页
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F.J. Sainz-Gonzalo; C. Elosua; M. Casimiro; C. Popovici; J.F. Fernandez-Sanchez; I. Fernandez; F.L. Ortiz; F.J. Arregui; I.R. Matias; A. Fernandez-Gutierrez;
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中图分类自动化技术及设备;
关键词
Optode; Europium (III) ions; Luminescence; Dip Coating; Plastic Coating;

机译：光电;铕（III）离子;发光;浸涂;塑料涂层;

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1. A novel luminescent optical fibre probe based on immobilized tridentate bis(phosphinic amide)-phosphine oxide for europium(Ⅲ) ion aqueous detection in situ [J] . F.J. Sainz-Gonzalo, C. Elosua, J.F. Fernandez-Sanchez, Sensors and Actuators . 2012,第期

机译：固定化三齿双（次膦酰胺）-氧化膦的新型发光光纤探针用于euro（Ⅲ）离子水溶液的原位检测
2. 3D water-stable europium metal organic frameworks as a multi-responsive luminescent sensor for high-efficiency detection of Cr2O72-, MnO4-, Cr3+ ions and SDBS in aqueous solution [J] . Yang Shuai-Liang, Yuan Yue-Ying, Sun Pei-Pei, New Journal of Chemistry . 2018,第24期

机译：3D水稳定的铕金属有机框架作为一种多响应发光传感器，用于高效检测CR2O72-，MNO4，Cr3 +离子和水溶液中的SDBS
3. Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties [J] . Papan Jelena, Jovanovic Dragana J., Vukovic Katarina, Optical Materials . 2016,第Nova期

机译：掺杂（（III）的A（2）Hf（2）O（7）（A = Y，Gd，Lu）纳米颗粒：退火温度，euro（III）浓度和主体阳离子对发光性能的影响
4. Europium(III) ion detection in water by a new luminescent optical fibre sensor [C] . F.J. Sainz-Gonzalo, C. Elosua, M. Casimiro, International Meeting on Chemical Sensors . 2012

机译：铕（III）通过新的发光光纤传感器在水中离子检测
5. Selective activation of terbium(III) and europium(III) luminescencewith triarylboron-functionnalized carboxylate ligands. And Luminescent 8-hydroxyquinoline dipicolylamine complexes as sensors for zinc(II) [D] . Varlan, Maria. 2012

机译：用三芳基硼官能化的羧酸盐配体选择性激活activation（III）和euro（III）发光。发光的8-羟基喹啉二聚烯丙基胺配合物作为锌（II）的传感器
6. Exceptional Oxygen Sensing Properties of New Blue Light-Excitable Highly Luminescent Europium(III) and Gadolinium(III) Complexes [O] . Sergey M. Borisov, Roland Fischer, Robert Saf, -1

机译：新型蓝光可激发的高发光Euro（III）和d（III）配合物的出色的氧传感特性
7. P1.3.5 Europium(III) ion detection in water by a new luminescent optical fibre sensor [O] . F. J. Sainz-Gonzalo, J. F. Fernández-Sánchez, A. Fernández-Gutiérrez, 2012

机译：P1.3.5通过新的发光光纤传感器在水中进行IOLOPIUM（III）
8. Optical fiber spectroscopy: A study of the luminescent properties of the europium ion for thermal sensors [R] . Buoncristiani, A. Martin 1992

机译：光纤光谱学：研究铕离子对热传感器的发光特性

Europium(III) ion detection in water by a new luminescent optical fibre sensor

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