Formation of Methyl Acrylate from Methyl Acetate and Formaldehyde Condensation over Solid Base Catalysts

机译：用固体碱催化剂从乙酸甲酯和甲醛缩合的甲基丙烯酸甲酯形成

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The vapor-phase aldol condensation of methyl acetate (MeOAC) with formaldehyde (HCHO) to form methyl acrylate was investigated over solid base catalysts. A variety of solid base catalysts were prepared by loading Cs_2O over SiO_2 or Al_2O_3 as the support materials. The properties of the solid base catalysts were characterized by XRD, BET and CO_2-TPD. The results of the vapor-phase aldol condensation indicated that SiO_2 and Al_2O_3 modified with Cs_2O showed high conversation of methyl acetate and high selectivity of methyl acrylate. 22.6% conversation of methyl acetate and 16.5% yield of acrylic acid and methyl acrylate were obtained over Cs-Al_2O_3. In addition, Cs-SiO_2 exhibited about 42% selectivity to methyl acetate. The high yield of acrylic acid and methyl acrylate is attributed to the high base property of catalysts.

机译：研究了用固体碱催化剂研究与甲醛（HCHO）与甲醛（HCHO）形成甲基丙烯酸甲酯的气相醛醇缩合。通过将Cs_2O或Al_2O_3作为载体材料加载Cs_2O或Al_2O_3来制备各种固体碱催化剂。通过XRD，BET和CO_2-TPD表征固体碱催化剂的性质。气相醛醇缩合的结果表明，用CS_2O改性的SiO_2和Al_2O_3显示出高乙酸甲酯和丙烯酸甲酯的高选择性的高串联。通过Cs-Al_2O_3获得22.6％甲基甲酯的羟基甲酸甲酯和16.5％丙烯酸甲酯和丙烯酸甲酯。此外，CS-SiO_2对乙酸甲酯的选择性约42％。丙烯酸和丙烯酸甲酯的高产率归因于催化剂的高碱性性质。

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《International Conference on Materials Science and Information Technology》|2013年||共5页
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Yanan Wang; Qunlong Wang; Huanhui Chen; Jialei Zhang; Zhirong Zhu;
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中图分类 TB3-53;
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Methyl acetate; Formaldehyde; Maehyl acrylate; Solid base catalysts; Cs2O;

机译：乙酸甲酯;甲醛;Maehyl 丙烯酸;固体碱催化剂;的Cs 2 O;

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1. RESPONSE TO 'LETTER TO THE EDITOR FOR THE ARTICLE "SPHERICAL P-MODIFIED CATALYSTS FOR HETEROGENEOUS CROSS-ALDOL CONDENSATION OF FORMALDEHYDE WITH METHYL ACETATE FOR METHYL ACRYLATE PRODUCTION," C. ZUO, C. LI, T. GE, X. GUO, S. ZHANG, CAN. J. CHEM. ENG. 2017, 95, 2104' [J] . Li Chunshan The Canadian Journal of Chemical Engineering . 2018,第4期

机译：响应“文章给予编辑”球形P改性催化剂的甲醛与甲基甲酯的甲基甲基甲酯的非均相交叉醛糖凝聚，“C. Zuo，C.LI，T.Ge，X. Gu，S 。张，可以。 J.Chem。 eng。 2017,95,2104'
2. LETTER TO THE EDITOR FOR THE ARTICLE "SPHERICAL P-MODIFIED CATALYSTS FOR HETEROGENEOUS CROSS-ALDOL CONDENSATION OF FORMALDEHYDE WITH METHYL ACETATE FOR METHYL ACRYLATE PRODUCTION," C. ZUO, C. LI, T. GE, X. GUO, S. ZHANG, CAN. J. CHEM. ENG. 2017, 95, 2104 [J] . Abbey Kirk J. The Canadian Journal of Chemical Engineering . 2018,第4期

机译：关于编辑的文章“球形P改性催化剂，用于甲醛的甲基丙烯酸甲酯的甲基丙烯酸甲酯的非均相交叉醛醇缩合，”Zuo，C.Li，T.Ge，X. Guo，S.张，能够。 J.Chem。 eng。 2017,95,2104
3. SPHERICAL P-MODIFIED CATALYSTS FOR HETEROGENEOUS CROSS-ALDOL CONDENSATION OF FORMALDEHYDE WITH METHYL ACETATE FOR METHYL ACRYLATE PRODUCTION [J] . Zuo Cuncun, Li Chunshan, Ge Tingting, The Canadian Journal of Chemical Engineering . 2017,第11期

机译：用于甲基丙烯酸甲酯的甲基甲基甲酯的甲醛的非均相交叉醛醇缩合的球形P-改性催化剂
4. Formation of Methyl Acrylate from Methyl Acetate and Formaldehyde Condensation over Solid Base Catalysts [C] . Yanan Wang, Qunlong Wang, Huanhui Chen, International Conference on Materials Science and Information Technology . 2013

机译：用固体碱催化剂从乙酸甲酯和甲醛缩合的甲基丙烯酸甲酯形成
5. Catalyst deactivation in the synthesis of methyl acetate from methyl ether using group VIII metal salts of phosphotungstic acid. [D] . Tartamella, Timothy Leonard. 1997

机译：使用磷钨酸的group族金属盐从甲醚合成乙酸甲酯时催化剂失活。
6. Roles of Lewis Acid Catalysts in Diels‐Alder Reactions between Cyclopentadiene and Methyl Acrylate [O] . Prof. Ken Sakata, Prof. Emeritus Dr. Hiroshi Fujimoto 2020

机译：Lewis酸催化剂在环戊二烯与丙烯酸甲酯之间的Diels-Alder反应中的作用
7. Synthesis of acrylates from methyl propionate, propionic acid and formaldehyde in the gas phase on solid catalysts [O] . Nazariy Lapychak, Volodymyr Ivasiv, Roman Nebesnyi, 2016

机译：固体催化剂气相中甲基丙酸甲酯，丙酸和甲醛的合成丙烯酸酯
8. Acid-base properties, deactivation, and in situ regeneration of condensation catalysts for synthesis of methyl methacrylate [R] . Gogate, M. R. , Spivey, J. J. , Zoeller, J. R. 1996

机译：用于合成甲基丙烯酸甲酯的缩合催化剂的酸碱性，失活和原位再生

Formation of Methyl Acrylate from Methyl Acetate and Formaldehyde Condensation over Solid Base Catalysts

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