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Preparation, characterization of Cu Nanowires and Their Tribological Property in Liquid Paraffin

机译:液体石蜡中Cu纳米线及其摩擦学性的制备,表征

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In order to synthesize morphology and structure-controlled nano-copper, chemical reduction synthesis method was used coalescing microwave-assisted and modification. Cu nanowires with diameters of 20 to 25nm and lengths of 1.2 to 2.1μm were yielded by reduction of copper acetate tetrahydrate of (1, 2)-propanediol system using ascorbic acid as a reductant, polyethylene sorbitan monooleate (Tween 80) as a modifier and by microwave-assisted heating. The microstructure of these nanowires has been characterized by XRD and TEM. The XRD patterns indicate that the lattice parameters of these Cu nanowires are enlarged about 1.162% while the lattice parameters of Cu nanospheres are reduced about 1.024%. The growth mechanism of Cu nanowires is also suspected. The anti-wear and reducing friction performance of liquid paraffin with either Cu nanowires or Cu nanospheres has been measured by ball-on-disk UMT-II tribometer. It is found that the tribological performance of liquid paraffin with nano-Cu is improved, and the enhancement of improvement with Cu nanowires is better than with Cu nanospheres.
机译:为了合成形态和结构控制的纳米铜,化学还原合成方法使用聚结微波辅助和改性。通过减少使用抗坏血酸作为还原剂的醋酸铜四水合物(1,2) - 丙二醇系统的铜乙酸四水合物,将聚乙烯脱水甘露糖醇单烯烃(Tween 80)作为改性剂和通过微波辅助加热。这些纳米线的微观结构已经通过XRD和TEM表征。 XRD图案表明,这些Cu纳米线的晶格参数大约1.162%,而Cu纳米球的晶格参数减少约1.024%。 Cu纳米线的生长机理也被怀疑。用Cu纳米线或Cu纳米球的液体石蜡的抗磨损和减少摩擦性能已经通过球盘UMT-II摩擦计测量。结果发现,液体石蜡与纳米-C的摩擦性能得到改善,并且通过Cu纳米​​线改善的增强优于Cu纳米球。

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