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Synthesis of ZnO/CuO and TiO2/CuO Nanocomposites for Light and Ultrasound Assisted Degradation of a Textile Dye in Aqueous Solution

机译:ZnO / CuO和TiO2 / CuO纳米复合材料的ZnO / CuO和TiO2 / CuO纳米复合材料在水溶液中纺织染料的光和超声辅助降解

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ZnO/CuO and TiO2/CuO nanocomposites with different Zn/Cu and Ti/Cu ratios were prepared using sol-gel method. The obtained composite samples were used as catalyst. Methylene blue was used as a model of textile dye to evaluate their photocatalytic, sonocatalytic and photosonocatalytic activities. X-ray diffraction and energy dispersive X-ray analysis confirmed that only monoclinic CuO and hexagonal wurtzite ZnO structures are present in ZnO/CuO nanocomposites, while in TiO2/CuO nanocomposites monoclinic CuO and anatase TiO2 structures were observed. The degradation of methylene blue indicated that the incorporation of CuO in ZnO/CuO and TiO2/CuO nanocomposites exhibited an appreciable higher photocatalytic activity, which was mainly attributed to the extended photoresponding range and more light energy could be utilized than pure ZnO and TiO2.
机译:使用溶胶 - 凝胶法制备具有不同Zn / Cu和Ti / Cu比率的ZnO / CuO和TiO 2 / CuO纳米复合材料。将得到的复合样品用作催化剂。亚甲基蓝色用作纺织染料的模型,以评估其光催化,儿童催化和曝光催化活动。 X射线衍射和能量色散X射线分析证实,只有单斜晶类CuO和六边形紫硝基钛矿结构存在于ZnO / CuO纳米复合材料中,而在TiO 2 / CuO纳米复合材料中观察到单斜替卡和锐钛矿TiO2结构。亚甲基蓝的降解表明CuO在ZnO / CuO和TiO 2 / CuO纳米复合材料中的掺入表现出可观的较高的光催化活性,其主要归因于延伸的光致相对的范围,并且可以利用比纯ZnO和TiO 2更高的光能。

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