Effect of Different Low-Molar Mass Electrolytes on the Viscometric Behaviour of Sodium Polystyrenesulfonate in Methanol-Water Mixed Solvent Media

机译：不同低摩尔质量电解对甲醇 - 水混合溶剂培养基中聚苯磺酸钠粘度特性的影响

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Precise measurements on the viscosities of sodium polystyrenesulfo- nate (NaPSS) in water as well as in methanol-water mixed solvent media have been reported in presence of NaCl, KCl, NaBr and KBr having concentrations of 0.1 and 0.5mol.L ~(-1) at 308.15 K with the polyelectrolyte concentrations in the range ～0.001 to ～0.012 eqv L ~(-1) . The reduced viscosities of the polyelectrolyte solutions vary linearly with polymer concentration for all the systems investigated which enabled us to determine the intrinsic viscosities of sodium polystyrenesulfonate in methanol-water mixtures using the Huggins equation. The coiling of the polyion chains are found to increase in the order: NaPSS-NaCl

机译：在NaCl，KCl，NaBr和Kbr的情况下，含有0.1和0.5mol.L的浓度的NaCl，Kcl，NaBr和Kbr〜（ - 1）在308.15 k下，聚电解质浓度范围为0.001至〜0.012 eqv l〜（-1）。聚电解质溶液的降低粘度随着所研究的所有系统的聚合物浓度而变化，使我们能够使用Huggins方程确定甲醇 - 水混合物中的聚苯磺酸钠的固有粘度。发现聚膜链的卷绕有序增加：水滴 - NaCl <水溶瘤 - Nabr <水溶蛋白-KCl <水溶蛋白-KBr。发现聚膜线圈的溶解度尺寸减少，因为基础的相对介电常数降低。本研究还表明，聚硫醚结构随着培养基中的盐浓度增加而变得更加紧凑。

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《International Conference: Kathmandu Symposia On Advanced Materials》|2016年|1 CD-ROM|共6页
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Ajaya Bhattarai; Bijan Das;
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中图分类合成树脂与塑料工业;
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intrinsic viscosities; methanol-water mixed solvent media; reduced viscosities; sodium polystyrenesulfonate;

机译：内在粘度;甲醇 - 水混合溶剂介质;降低粘度;钠聚苯乙烯磺酸钠;

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1. Effect of Different Low-Molar Mass Electrolytes on the Viscometric Behaviour of Sodium Polystyrenesulfonate in Methanol–Water Mixed Solvent Media [J] . Ajaya Bhattarai, Bijan Das Macromolecular symposia . 2016,第Null期

机译：不同摩尔质量的低质量电解质对聚苯乙烯磺酸钠在甲醇-水混合溶剂介质中粘度行为的影响
2. Solvodynamic Properties of Sodium Polystyrenesulfonate in Methanol-Water Mixed Solvent Media in Absence and in the Presence of a Salt Using Viscometric Method [J] . Ajaya Bhattarai, Bijan Das Macromolecular symposia . 2012,第1期

机译：聚苯乙烯磺酸钠在甲醇和水混合溶剂介质中（在无盐条件下）的粘度测定法
3. Coiling/uncoiling behaviour of sodium polystyrenesulfonate in 2-ethoxyethanol-water mixed solvent media as probed using viscometry [J] . Ranjit De, Bijan Das Polymer international . 2014,第11期

机译：粘度测定法研究2-苯乙烯-水-混合溶剂介质中聚苯乙烯磺酸钠的卷曲/开卷行为
4. Effect of Different Low-Molar Mass Electrolytes on the Viscometric Behaviour of Sodium Polystyrenesulfonate in Methanol-Water Mixed Solvent Media [C] . Ajaya Bhattarai, Bijan Das International Conference: Kathmandu Symposia On Advanced Materials . 2016

机译：不同低摩尔质量电解对甲醇 - 水混合溶剂培养基中聚苯磺酸钠粘度特性的影响
5. Generation of Novel Solid-State Electrolyte: Co-Crystals of Organic Solvent and Lithium (Or Sodium) Salts [D] . Fall, Birane. 2020

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6. Monovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries [O] . Ali Firouzi, Ruimin Qiao, Shahrokh Motallebi, -1

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8. Compatibility of Nickel Electrolyte Containing Sodium Sulfate with a Solvent Extraction System [R] . Holmes, R. A. , Nilsen, D. N. , Siemens, R. E. 1983

机译：含硫酸钠的镍电解液与溶剂萃取系统的相容性

Effect of Different Low-Molar Mass Electrolytes on the Viscometric Behaviour of Sodium Polystyrenesulfonate in Methanol-Water Mixed Solvent Media

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