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The Role of Solvent Mixture, Acetic Acid and Water in the Formation of CA Membrane for CO2/N2 Separation

机译:溶剂混合物,乙酸和水在Ca膜形成中的作用,用于CO 2 / N2分离

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The improvement of Carbon dioxide (CO2) separation efficiency from flue gases to reduce the total energy cost of sequestration technologies in coal-fired power plants has been identified as a high-priority research area. In the past three decades, membranes have attracted the attention of chemists and engineers due to their unique separation principles (i.e., selective transport and efficient separation compared to other unit operations). In this study, the formation of cellulose acetate (CA) membrane for CO2/nitrogen (N2) separation was investigated by wet phase inversion. In order to modify the CA membrane structure, different concentration ratio of solvent mixture (acetic acid:water), acetic acid and water were studied. The CA membranes were analyzed by Fourier transform infrared spectroscopy (FTIR). The separation results supported by the characterization, where the best formulate membrane with solvent mixture ratio of 70:30 (acetic acid:water), acetic acid concentration of 63 wt% and water concentration of 27 wt% had high CO2 permeance of 400.92 GPU and slightly better CO2/N2 separation performance at 32.92 as compared to others literature.
机译:从烟道气中提高二氧化碳(CO2)分离效率,以降低燃煤发电厂中封存技术的总能量成本已被识别为高优先级研究区域。在过去的三十年中,由于其独特的分离原理(即,与其他单元操作相比,选择性运输和有效分离,膜引起了化学家和工程师的注意。在该研究中,通过湿相倒反相研究了用于CO 2 /氮(N2)分离的醋酸纤维素(CA)膜的形成。为了改变Ca膜结构,研究了溶剂混合物(乙酸:水),乙酸和水的不同浓度比。通过傅里叶变换红外光谱(FTIR)分析Ca膜。表征支持的分离结果,其中最佳配制膜的溶剂混合比为70:30(乙酸:水),乙酸浓度为63wt%,水浓度为27wt%,具有400.92 gpu的高二氧化碳渗透率和与其他文献相比,32.92的CO 2 / N2分离性能略高于32.92。

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