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Molybdenum Oxide Particles Doped in Hole Transport Layer to Enhance the Efficiency of Flexible Polymer Solar Cells

机译:掺杂在空穴传输层中的氧化钼颗粒以提高柔性聚合物太阳能电池的效率

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Five PEDOT:PSS:MoO_3 volume ratios (1:1, 1:2, 1:3, 1:4, 1:5) hybrid hole transport layer (HTL) were prepared by solution processed method. The cell structure was PET/ITO/PEDOT:PSS:MoO_3/P3HT:PCBM/Ca/Al. We investigated the effect of MoO_3 added into the traditional PEDOT:PSS hole transfer layer on the photovoltaic performance. From these results, we found that the short circuit current density (J_(sc)), fill factor (FF) and power conversion efficiency PCE of the cells with M0O3 are always higher than those of cell without MoO_3.The short-circuit current density, fill factor and power conversion efficiency of cells increased with increasing MoO_3 volume ratio from 1:1 to 1:3 and then decreased slightly when the volume ratio increased to 1:4 and 1:5. The cell with 1:3 volume ratio exhibited the highest J_(sc) of 9.41 mA/cm2, an increase of 22%, and the highest PCE of 2.74%, an increase of 39%, compared to the controlled cell using PEDOT:PSS layer. The addition of M0O3 increased the probability of exciton dissociation due to its high hole mobility, thereby enhancing the J_(sc) and FF.
机译:五个PEDOT:PSS:MOO_3体积比(1:1,1:2,1:3,1:4,1:5)通过溶液加工方法制备杂化空穴传输层(HTL)。电池结构是PET / ITO / PEDOT:PSS:MOO_3 / P3HT:PCBM / CA / A1。我们调查了MOO_3加入传统佩托的效果:PSS孔转移层对光伏性能。从这些结果中,我们发现,带有M0O3的单元的短路电流密度(J_(SC)),填充因子(FF)和电源转换效率PCE总是高于电池的电池,而没有Moo_3。短路电流密度,细胞的填充因子和电力转换效率随着1:1至1:3的增加而增加,然后当体积比增加到1:4和1:5时,然后略微降低。与1中的单元:3的体积比表现出最高的J_9.41毫安/ cm2时,增加了22%,而2.74%的最高PCE,增加了39%,相比于使用PEDOT受控细胞(SC):PSS层。由于其高空穴迁移率,增加M0O3增加了激子解离的概率,从而增强了J_(SC)和FF。

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