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Crystallization behavior of sheared polyamide 66

机译:剪切聚酰胺的结晶行为66

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The application of fast scanning chip calorimetry (FSC) for analysis of sheared polyamide 66 (PA 66) provided quantitative insight to the effect of shear flow and flow-induced formation of crystallization precursors/nuclei on the subsequent crystallization in a wide range of temperatures. In the high-temperature, heterogeneous-nucleation range, there is a direct relationship between the amount of specific work supplied to the melt and the acceleration of crystallization, presumably due in part to increased nucleation density of the sheared samples. This information is directly applicable to polymer engineering applications where the formation of crystalline domains during processing often occurs at rapid-cooling conditions. Analysis of the structure at the micrometer-length scale of sheared PA 66 by polarized-light optical microscopy (POM) revealed large shish-kebab structures.
机译:快速扫描芯片量热法(FSC)用于剪切聚酰胺66(PA 66)的分析提供了定量洞察剪切流动和流动诱导的结晶前体/核的效果对随后的各种温度的结晶。在高温,异质成核范围内,提供给熔体的特定工作量与结晶加速之间的直接关系,可能是部分含有剪切样品的成核密度。该信息可直接适用于聚合物工程应用,其中在加工过程中形成结晶结构域经常发生在快速冷却条件下。通过偏振光光学显微镜(POM)剪切PA 66微米长度法的结构分析(POM)揭示了大型烤肉串结构。

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