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Experimental investigation of concentration yields of liquid phase exfoliated graphene in organic solvent media

机译:有机溶剂培养基中液相剥落石墨烯浓度产率的实验研究

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The main purpose of this work is to experimentally investigate the concentration yields of exfoliated Graphene in organic solvents with the variation of different centrifugation speeds(rpm).Graphene was effectively fabricated by one of the most convenient chemical processing approach liquid-phase exfoliation(LPE)of graphite in two different organic solvent N-Methyl-2-Pyrrolidone(NMP)and N,N-dimethylformamide(DMF).After exfoliation separated supernatant dispersions were preserved into the other tube as product.Similar procedure was repeated with same parameter and same graphite for both of the solvents.FESEM analyses of the exfoliated Graphene samples revealed the presence of few layers of Graphene flakes stacking.Analysis of the Raman spectrum of the samples it was revealed that the precursor graphite flakes was converted to Graphene sheets.Concentrations of graphene suspensions in both solvents were measured from separately prepared standard graphs using Beer's law with the aid of UV-vis absorbance spectroscopy.Estimated exfoliated graphene concentration was acquired higher for lower centrifugation(rpm)for both of the solvent.It was also seen that for the same rpm concentration of Graphene was higher in NMP than that of in DMF.
机译:本作作品的主要目的是通过不同离心速度(RPM)的变化进行实验地研究剥离石墨烯的浓度产率(RPM).Prapheth通过最方便的化学处理方法液相剥离(LPE)有效地制造。在两种不同的有机溶剂N-甲基-2-吡咯烷酮(NMP)和N,N-二甲基甲酰胺(DMF)中的石墨。将剥离分离的上清液分散体中的将剥离分离的上清液分散在另一个管中作为产物。用相同的参数重复混合过程脱落的石墨烯样品的溶剂的富硒分析显示出少量石墨烯片的存在。样品的拉曼光谱分析显示,将前体石墨薄片转化为石墨烯片。石墨烯的间融合借助于UV - 使用啤酒法测量两种溶剂中的悬浮液,从单独制备的标准图测量。对吸光度光谱法获取较低离心(RPM)的次数升温的剥落石墨烯浓度,也可以看出,对于相同的RPM浓度,石墨烯浓度高于DMF中的浓度。

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