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Enhanced Photoelectrochemical Water Splitting of Hydrothermally-Grown ZnO and Yttrium-doped ZnO NR Arrays

机译:增强热量生长ZnO和钇掺杂ZnO阵列的光电化学水分裂

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Undoped and Y doped ZnO nanorods (YZO NRs) were prepared by hydrothermal method. The as-prepared ZnO and YZO NRs with different Y/Zn molar ratios were used as anodes for electrochemical water splitting. Then, photoelectrochemical (PEC) water splitting performances of YZO NRs were tested. When compared with pristine ZnO NRs, the photocurrent density generated with yttrium doped zinc oxide NR as electrode was higher(1.2 mA cm~(-2) ) than that obtained with pristine ZnO NRs (0.25 mA cm~(-2)), at 0.2 V vs. Ag/ AgCl using samples of 1.2 mol % of yttrium. This performance corresponds to calculated photo-conversion efficiency of 0.40%, at a low potential (-0.38V vs Ag/AgCl) of the non-doped ZnO NR film. Keuwords: Yttrium doped zinc oxide nanorod, Sol gel deposition, Structural properties
机译:通过水热法制备未掺杂和Y掺杂的ZnO纳米棒(YZO NRS)。具有不同Y / Zn摩尔比的制备的ZnO和YZO NRS用作电化学水分裂的阳极。然后,测试了光电化学(PEC)yzo NRS的水分裂性能。与原始ZnO NRS相比,用钇掺杂的氧化锌Nr产生的光电流密度高于原始ZnO NRS(0.25 mA cm〜(-2)),较高(1.2 mA cm〜(-2)),在使用1.2摩尔%的钇的样品0.2V与Ag / AgCl。该性能对应于在非掺杂ZnO NR膜的低电位(-0.38V Vs Ag / AgCl)的低电位(-0.38V Vs Ag / AgCl)的下计算出的光转化效率。 Keuwords:钇掺杂氧化锌纳米棒,溶胶凝胶沉积,结构性能

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