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The Influence of Nano Fluid Compared With Polyethylene Glycol and Surfactant on Wettability Alteration of Carbonate Rock

机译:与聚乙二醇和表面活性剂相比纳米液对碳酸盐岩润湿性改变的影响

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The purpose of this research is to enhance oil recovery of the carbonate rock by wettability alteration using silica suspended in brine, polyethylene glycol (PEG), and sodium dodecyl sulfate (SDS). Hydrophilic silica with a different mean Nano size 52, 65 nm was synthesized from local sand by a chemical method. The synthesized Nano silica was characterized by AFM to determine the average particle size and distribution, and surface area was measured by physical adsorption of nitrogen. The wettability alteration was studied by dipping the carbonate rock in different concentrations of Nano silica (0.01-lwt. %) for a certain silica size suspended in brine for different dipping times as well as for PEG and SDS. The contact angle was measured before and after each run in order to recognize the extent of affinity change (wettability) of the carbonate. The results showed that the Nano particles were more reactive due to their high surface area these particles had the highest potential for wettability alteration. The contact angle decreased with decrease particle size and increase concentration. The PEG polymer and SDS surfactant showed less influence on wettability alteration compared with Nano fluids.
机译:本研究的目的是通过使用悬浮在盐水,聚乙二醇(PEG)和十二烷基硫酸钠(SDS)中的二氧化硅通过润湿性改变来提高碳酸盐岩石的吸收。通过化学方法从局部砂中合成具有不同平均纳米尺寸52,65nm的亲水性二氧化硅。合成的纳米二氧化硅通过AFM的特征在于确定平均粒度和分布,通过物理吸附氮气测量表面积。通过将不同浓度的纳米二氧化硅(0.01-LWT%)浸入悬浮在盐水中的某种二氧化硅尺寸以及PEG和SDS的某种二氧化硅尺寸来研究润湿性改变。在每次运行之前和之后测量接触角,以识别碳酸酯的亲和变化(润湿性)的程度。结果表明,由于它们的高表面积,纳米颗粒具有更高的反应性,这些颗粒具有最高的润湿性变化的潜力。通过降低粒度和增加浓度,接触角下降。与纳米液相比,PEG聚合物和SDS表面活性剂对润湿性改变的影响较小。

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