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Effect of Mixing on the Optical Parameters of Polymer Blend (PMMA:PVC:PS) Thin Films

机译:混合对聚合物共混物光学参数的影响(PMMA:PVC:PS)薄膜

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The thin films have been prepared using casting method at normal weather conditions of pressure and temperature. The films treated thermally for three hours at 45 C. The UV-VIS double beam technique used to determine absorption and reflection spectrum. The thickness of the prepared thin films is measured using a handheld gauge of coating thickness measurement. Excel and MATLAB program used to calculate and simulate parameters and figures. The optical properties of PMMA:PVC:PS mixtures have been investigated. There is a clear change in the optical parameters due to mixing ratio. The result shows the indirect energy gap values reduced from 1.58 to 1.9 electron-volts. Mix a ratio of PMMA, PVC & PS leads to enhance some of the optical parameters like optical energy gap, absorbance, extinction coefficient and optical conductivity. The four kinds of thin films have different properties: The polymer blend (50%PMMA:25%PVC:25%PS) has the smallest values of the energy gap and linear refractive index, and the highest extinction coefficient values. The polymer blend (25%PMMA:25%PVC:50%PS) has a small value of energy gap and the best optical conductivity. The polymer blend (25%PMMA:50%PVC:25%PS) has the highest Urbach energy and absorption for the short wavelength (370 to 620 nm). The polymer blend (50%PVC:50%PS) has a good reflection, linear refractive index and skin depth, but it has the lowest values of extinction coefficient and optical conductivity.
机译:在正常的天气和温度下,使用铸造方法制备薄膜。将薄膜在45℃下热量处理3小时。用于确定吸收和反射光谱的UV-VIS双光束技术。使用涂布厚度测量的手持量测量测量制备的薄膜的厚度。 Excel和Matlab程序用于计算和模拟参数和图。 PMMA的光学性质:PVC:PS混合物已经研究过。由于混合比率,光学参数有明显的变化。结果表明间接能隙值从1.58降至1.9电子伏。混合PMMA,PVC&PS的比率导致提高光学能隙,吸光度,消光系数和光学电导率等一些光学参数。四种薄膜具有不同的性质:聚合物共混物(50%PMMA:25%PVC:25%PS)具有能量隙和线性折射率的最小值,以及最高消光系数值。聚合物共混物(25%PMMA:25%PVC:50%PS)具有较小的能隙值和最佳光导。聚合物共混物(25%PMMA:50%PVC:25%PS)具有最高的URBACH能量和短波长(370至620nm)的吸收。聚合物共混物(50%PVC:50%PS)具有良好的反射,线性折射率和肤浅,但它具有光消光系数和光导的最低值。

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