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Production of Poly(carbonate-co-ether) via Catalytic Polymerization of Epoxidized Linseed Oil, Propylene Oxide and Carbon Dioxide

机译：通过环氧化亚麻籽油，环氧丙烷和二氧化碳的催化聚合生产聚（碳酸盐 - 共醚）

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Poly-(carbonate-co-ether) was synthesized via catalytic polymerization between epoxidized linseed oil [ELO], propylene oxide (PO) and carbon dioxide (CO2) using heterogeneous catalyst namely Co-Zn double metal cyanide (Co-Zn DMC). The influence of polymerization time was studied. It was revealed that the properties of the resultant polymers were affected by the polymerization time. Within the range of polymerization time studied, the maximum average molecular weight (Mn) of the resultant polymer obtained was 6.21 x 10~5 g.moH with polydispersity index (PDI) of 1.05 at reaction time of 24 hours.

机译：使用异质催化剂即Co-Zn双金属氰化物（Co-Zn DMC），通过环氧化亚麻籽油[ELO]，环氧丙烷（PO）和二氧化碳（CO2）之间的催化聚合来合成聚 - （碳酸酯 - 共醚）。研究了聚合时间的影响。揭示了所得聚合物的性质受聚合时间的影响。在所研究的聚合时间范围内，得到的所得聚合物的最大平均分子量（MN）为6.21×10〜5g.mOH，在24小时的反应时间下，多分散指数（PDI）为1.05。

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《International Rubber Conference》|2019年|207 p.|共6页
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F W Shaarani; J J Boil; R N Hakim;
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中图分类工程材料学;
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1. Synthesis of vegetable-oil based polymer by terpolymerization of epoxidized soybean oil, propylene oxide and carbon dioxide [J] . Farra Wahida Shaarani, Jordi J. Bou The Science of the Total Environment . 2017,第Nova15期

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2. Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) by Regio- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide [J] . Koji Nakano, Shinichi Hashimoto, Mitsuru Nakamura Angewandte Chemie . 2011,第21期

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3. Poly(propylene carbonate). 1. More about poly(propylene carbonate) formed from the copolymerization of propylene oxide and carbon dioxide employing a zinc glutarate catalyst [J] . Chisholm MH., Navarro-Llobet D., Zhou ZP. Macromolecules . 2002,第17期

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4. Production of Poly(carbonate-co-ether) via Catalytic Polymerization of Epoxidized Linseed Oil, Propylene Oxide and Carbon Dioxide [C] . F W Shaarani, J J Boil, R N Hakim International Rubber Conference . 2019

机译：通过环氧化亚麻籽油，环氧丙烷和二氧化碳的催化聚合生产聚（碳酸盐 - 共醚）
5. Homogeneously catalytic hydroformylation of propylene in supercritical carbon dioxide. [D] . Guo, Yang. 1998

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6. A Novel One-Pot Synthesis of Poly(Propylene Carbonate) Containing Cross-Linked Networks by Copolymerization of Carbon Dioxide Propylene Oxide Maleic Anhydride and Furfuryl Glycidyl Ether [O] . Lijun Gao, Xianggen Chen, Xiangjun Liang, 2019

机译：通过二氧化碳环氧丙烷顺丁烯二酸酐和糠基缩水甘油醚的共聚反应新颖地合成含有交联网络的聚碳酸亚丙酯
7. Synthesis of vegetable-oil based polymer by terpolymerization of epoxidized soybean oil, propylene oxide and carbon dioxide [O] . Farra Wahida Shaarani, Jordi J. Bou 2017

机译：环氧化大豆油，环氧丙烷和二氧化碳的三聚合，植物油基聚合物的合成

Production of Poly(carbonate-co-ether) via Catalytic Polymerization of Epoxidized Linseed Oil, Propylene Oxide and Carbon Dioxide

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