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Extracting copper(II)ions from model solutions with carbon containing adsorption material

机译:用含碳吸附材料从模型溶液中提取铜(II)离子

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A method for purifying model aqueous solutions from Cu~(2+)ions with carbon-containing adsorption material obtained by thermal modification of kieselghur sludge is proposed.Waste kieselghur sludge is characterized by an organic-mineral composition,which is formed in the technology of refining vegetable oil at the winterization stage i.e.removing waxes and wax-like substances at a temperature corresponding to their crystallization.As a result of heat treatment of the sludge at a temperature of 500 °C,carbonization of organic substances occurs with the formation of a carbon layer on the surface of diatomite particles and the formation of a carbon-containing adsorption material.The concentrations of Cu~(2+)ions in model aqueous solutions was determined out by photometric method.It was shown that the maximum sorption of copper ions occurs in the range of pH 6-7 and at the consumption of the adsorbent 1 g per 100 cm~3of solution.The kinetic dependences of the adsorption process are studied - the maximum efficiency of extracting copper ions reaches 15 and 30 minutes at the initial concentration of solutions 10 and 25 mg/dm3,respectively.The adsorption capacity of the carbon-containing material was 14.3 mg/g,the nature of the process is monomolecular.
机译:提出了一种从Cu〜(2+)离子与通过KIESelghur污泥的热改性获得的含碳吸附材料纯化Cu〜(2+)离子的方法。废物kieselghur污泥的特征在于,有机矿物组合物在技术中形成在冬季化型蜡的植物油在与其结晶相对应的温度下的蜡型蜡和蜡状物质。在500℃的温度下,污泥的热处理结果,有机物质的碳化随着形成的形成发生硅藻土颗粒表面上的碳层和含碳吸附材料的形成。通过光度法测定模型水溶液中Cu〜(2+)离子的浓度。表明铜离子的最大吸附发生在pH 6-7的范围内,并且在每100厘米〜3℃的吸附剂1g的消耗中。研究了吸附过程的动力学依赖性 - 分别提取铜离子的最大效率在溶液10和25mg / dm3的初始浓度下达到15和30分钟。含碳材料的吸附能力为14.3mg / g,该方法的性质是单分子。

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