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Flame stability limits of Li-ion battery electrolyte solvents with organophosphorus compounds addition on a wick-stabilized flame

机译:锂离子电池电解液溶剂的火焰稳定性限制,有机磷化合物加入芯稳定的火焰

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The limiting oxygen concentration (LOC) method in conjunction with a wick burner, called wick-LOC method, is used to determine the flame stability limits of Li-ion battery electrolyte solvents with organophosphorus compounds (OPCs) addition. Two modes of wick-stabilized flame are found, namely, wake flame and full flame. With the addition of OPC, two distinct extinction behaviors occur according to the different flame modes near extinction. The flame stability limits are measured as a function of OPC addition for both flame modes. The wake flame is shown to be consistently more stable at low levels of OPC addition. However, once the OPC addition exceeds a critical amount, the full flame shows higher stability with a lower LOC than the wake flame. In the most stable flame mode, the regime switches from the wake flame to the full flame with increasing OPC addition, and they are defined correspondingly as 'blow-off regime' and 'quenching regime'.
机译:将氧气浓度(LOC)方法与芯燃烧器相结合,称为WICK-LOC方法,用于确定锂离子电池电解质溶剂的火焰稳定性限制,具有有机磷化合物(OPCS)加入。发现了两种芯稳定的火焰,即唤醒火焰和充分的火焰。随着APC的添加,根据濒临灭绝的不同火焰模式发生两个不同的消光行为。作为两个火焰模式的OPC添加的功能,测量火焰稳定性限制。唤醒火焰显示在低水平的OPC添加时始终如一更稳定。然而,一旦OPC加法超过临界量,全火焰显示出比唤醒火焰更低的位置更高的稳定性。在最稳定的火焰模式中,通过增加OPC添加,该制度从唤醒火焰切换到全火焰,并且它们相应地定义为“爆炸制度”和“淬火制度”。

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