首页> 外文会议>RAM 2013 >Effect of Iron Substitution In Pyrochlore Type Semiconducting Oxides: CaCe_(0.6)Mn_(0.4)Sn_(1-x)Fe_xNbO_(7-δ) (x = 0, 0.2, 0.4 and 0.6) For High Temperature NTC Thermistor Applications
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Effect of Iron Substitution In Pyrochlore Type Semiconducting Oxides: CaCe_(0.6)Mn_(0.4)Sn_(1-x)Fe_xNbO_(7-δ) (x = 0, 0.2, 0.4 and 0.6) For High Temperature NTC Thermistor Applications

机译:纤维型半导体氧化物中铁取代的影响:高温NTC热敏电阻应用的CACE_(0.6)MN_(0.4)SN_(0.4)SN_(1-X)FE_XNBO_(7-Δ)(x = 0,0.2,0.4和0.6)

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摘要

Iron substituted Pyrochlore structed semiconducting oxides, prepared by solid state reaction method, exhibit Negative Temperature Coefficient of Resistance (NTCR) behavior for a wide range of temperature from room temperature to 600°C. The impedance study of the system provided insight to the bulk or grain contribution in the electrical properties of the system. We were able to decrease the activation energy for conduction by Fe substitution and enhance the sensitivity values without affecting the thermistor constant considerably. The conductivity variation with temperature follows the Arrhenius relation.
机译:铁取代的烧火结构半导体氧化物通过固态反应方法制备,表现出负温度的抗性系数(NTCR)行为,用于从室温至600℃的宽范围的温度。系统的阻抗研究提供了对系统的电气性质的散装或谷物贡献的洞察。我们能够降低Fe替代的激活能量,并增强灵敏度值,而不会显着影响热敏电阻恒定。具有温度的电导率变化遵循Arrhenius关系。

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